TY - JOUR
T1 - Zinc complex of N-confused calix[4]phyrin
AU - Furuta, Hiroyuki
AU - Ishizuka, Tomoya
AU - Osuka, Atsuhiro
N1 - Funding Information:
T.I. thanks JSPS for a Research Fellowship for Young Scientists.
PY - 2003/4/1
Y1 - 2003/4/1
N2 - A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by 1H NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 Å longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on η1-coordination with the inner-core-carbon in 2-Zn.
AB - A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by 1H NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 Å longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on η1-coordination with the inner-core-carbon in 2-Zn.
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U2 - 10.1016/S1387-7003(02)00797-9
DO - 10.1016/S1387-7003(02)00797-9
M3 - Article
AN - SCOPUS:0037395779
SN - 1387-7003
VL - 6
SP - 398
EP - 401
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 4
ER -