Thermoelectric properties of chevrel-type sulfides AMo6S8 (A=Fe, Ni, Ag, Zn, Sn, Pb, Cu)

Toshiki Tsubota, Michitaka Ohtaki, Koichi Eguchi

    研究成果: ジャーナルへの寄稿学術誌査読

    13 被引用数 (Scopus)

    抄録

    Thermoelectric properties of Chevrel-type sulfides AMo6S8 (A=Fe, Ni, Ag, Zn, Sn, Pb, Cu) were investigated with respect to many advantageous characteristics of the Chevrel compounds for thermoelectric applications. The electrical conductivity, σ, was 102.5 S·cm-1<σ<103 S·cm-1 for most of the samples from room temperature to 1000°C; AgMo6S8 gave the largest σ up to 250°C. The Seebeck coefficient, S, was positive for all the samples, indicating the p-type conduction. All the S values were 10 μV·K-1<S<80 μV· K-1, and AgMo6S8 showed the smallest S, probably owing to the higher hole concentration for A=Ag compared to other samples. The maximum S2σ value was attained by SnMo6S8, reaching ca. 1.7 × 10-4 W·m-1· K-2 at 800°C. All the κ values were 1 W·m-1·K-1<κ<3 W·m-1·K-1 from room temperature to 1000°C. The maximum Z value was ca. 0.07 × 10-3 K-1 attained by SnMo6S8 at 800°C.

    本文言語英語
    ページ(範囲)697-701
    ページ数5
    ジャーナルJournal of the Ceramic Society of Japan
    107
    8
    DOI
    出版ステータス出版済み - 1999

    !!!All Science Journal Classification (ASJC) codes

    • セラミックおよび複合材料
    • 化学一般
    • 凝縮系物理学
    • 材料化学

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