Temperature dependent 1H NMR study of the substrate complex derived from zinc(II) perchlorate, (R,R)-4,6-dibenzofurandiyl-2,2'-bis(4- phenyloxazoline), and 3-acetyl-2-oxazolidinone. Evidence for octahedral structure of the substrate complex

Shuji Kanemasa, Yoji Oderaotoshi, Junji Tanaka, Eiji Wada

研究成果: ジャーナルへの寄稿学術誌査読

19 被引用数 (Scopus)

抄録

Temperature dependent 1H NMR study has been performed on the substrate complex derived from zinc(II) perchlorate, (R,R)-4,6-dibenzofurandiyl-2,2'- bis(4-phenyloxazoline), and 3-acetyl-2-oxazolidinone in deuteriodichloromethane. At room temperature, two isomers of octahedral substrate complexes are rapidly exchanging through a trigonal bipyramid intermediate. Liberation of the DBFOX/Ph ligand from the substrate complex can not be observed in a wide range of temperature, showing high stability of the DBFOX/ph · Zn(CIO4)2 complex.

本文言語英語
ページ(範囲)7521-7524
ページ数4
ジャーナルTetrahedron Letters
39
41
DOI
出版ステータス出版済み - 10月 8 1998

!!!All Science Journal Classification (ASJC) codes

  • 生化学
  • 創薬
  • 有機化学

フィンガープリント

「Temperature dependent 1H NMR study of the substrate complex derived from zinc(II) perchlorate, (R,R)-4,6-dibenzofurandiyl-2,2'-bis(4- phenyloxazoline), and 3-acetyl-2-oxazolidinone. Evidence for octahedral structure of the substrate complex」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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