Tailoring the lithium-ion conductivity of Li2OHBr by substitution of bromine with other halogens

Manoj Krishna Sugumar; Takayuki Yamamoto; Munekazu Motoyama; Yasutoshi Iriyama

doi:10.1246/cl.200778

Tailoring the lithium-ion conductivity of Li₂OHBr by substitution of bromine with other halogens

Manoj Krishna Sugumar, Takayuki Yamamoto, Munekazu Motoyama, Yasutoshi Iriyama

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

10 被引用数 (Scopus)

抄録

We report that mixed-halogen anti-perovskite-type Li₂OHBr₁¹_xX_x (X = Cl, I and x = 01) materials are prepared by room temperature ball-milling process, and investigate how the halogen mixing affects the total Li⁺ conductivity. Both solid solution ranges and lattice constants depend on the species of X. Among them, though X = I compounds form solid solution in narrow range of x smaller than 0.15, Li₂OHBr_0.9I_0.1 shows the largest lattice constant and the highest total ionic conductivity at 25 °C (σ₂₅) of 4.9

本文言語	英語
ページ（範囲）	448-451
ページ数	4
ジャーナル	Chemistry Letters
巻	50
号	3
DOI	https://doi.org/10.1246/cl.200778
出版ステータス	出版済み - 3月 2021
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

化学一般

文献へのアクセス

10.1246/cl.200778

他のファイルとリンク

引用スタイル

@article{f192b8a11bde4ebbada06286223fe033,

title = "Tailoring the lithium-ion conductivity of Li2OHBr by substitution of bromine with other halogens",

abstract = "We report that mixed-halogen anti-perovskite-type Li2OHBr11xXx (X = Cl, I and x = 01) materials are prepared by room temperature ball-milling process, and investigate how the halogen mixing affects the total Li+ conductivity. Both solid solution ranges and lattice constants depend on the species of X. Among them, though X = I compounds form solid solution in narrow range of x smaller than 0.15, Li2OHBr0.9I0.1 shows the largest lattice constant and the highest total ionic conductivity at 25 °C (σ25) of 4.9",

author = "Sugumar, {Manoj Krishna} and Takayuki Yamamoto and Munekazu Motoyama and Yasutoshi Iriyama",

note = "Publisher Copyright: {\textcopyright} 2021 The Chemical Society of Japan",

year = "2021",

month = mar,

doi = "10.1246/cl.200778",

language = "English",

volume = "50",

pages = "448--451",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "3",

}

TY - JOUR

T1 - Tailoring the lithium-ion conductivity of Li2OHBr by substitution of bromine with other halogens

AU - Sugumar, Manoj Krishna

AU - Yamamoto, Takayuki

AU - Motoyama, Munekazu

AU - Iriyama, Yasutoshi

PY - 2021/3

Y1 - 2021/3

N2 - We report that mixed-halogen anti-perovskite-type Li2OHBr11xXx (X = Cl, I and x = 01) materials are prepared by room temperature ball-milling process, and investigate how the halogen mixing affects the total Li+ conductivity. Both solid solution ranges and lattice constants depend on the species of X. Among them, though X = I compounds form solid solution in narrow range of x smaller than 0.15, Li2OHBr0.9I0.1 shows the largest lattice constant and the highest total ionic conductivity at 25 °C (σ25) of 4.9

AB - We report that mixed-halogen anti-perovskite-type Li2OHBr11xXx (X = Cl, I and x = 01) materials are prepared by room temperature ball-milling process, and investigate how the halogen mixing affects the total Li+ conductivity. Both solid solution ranges and lattice constants depend on the species of X. Among them, though X = I compounds form solid solution in narrow range of x smaller than 0.15, Li2OHBr0.9I0.1 shows the largest lattice constant and the highest total ionic conductivity at 25 °C (σ25) of 4.9

UR - http://www.scopus.com/inward/record.url?scp=85126561250&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85126561250&partnerID=8YFLogxK

U2 - 10.1246/cl.200778

DO - 10.1246/cl.200778

M3 - Article

AN - SCOPUS:85126561250

SN - 0366-7022

VL - 50

SP - 448

EP - 451

JO - Chemistry Letters

JF - Chemistry Letters

IS - 3

ER -