Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 x 3] square grid generated by a strict self-assembly process

Liang Zhao, Zhiqiang Xu, Laurence K. Thompson, Sarah L. Heath, David O. Miller, Masaaki Ohba

研究成果: ジャーナルへの寄稿学術誌査読

92 被引用数 (Scopus)

抄録

A ligand with a linear arrangement of three coordination pockets produces a Cu9O12, alkoxide-bridged, square grid of closely spaced copper centers (see picture) in high yield by a strict self-assembly process. Orthogonal bridging connections within the grid lead to dominant intramolecular ferromagnetic coupling with a high-spin ground state.

本文言語英語
ページ(範囲)3114-3117
ページ数4
ジャーナルAngewandte Chemie - International Edition
39
17
DOI
出版ステータス出版済み - 9月 1 2000

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学一般

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