Synthesis, structure and magnetic properties of a cyano-bridged dinuclear compound fac-{[FeIII(pzTp)(CN)2(μ-CN)] Cu II(TPyA)}·Et2O·ClO4 (pzTp = tetrakis(pyrazolyl)borate)

Da Yu Wu, Osamu Sato

研究成果: ジャーナルへの寄稿学術誌査読

3 被引用数 (Scopus)

抄録

The reaction of tricyanometallate precursor, (Bu4N)[(pzTp)Fe(CN) 3] with Cu(ClO4)2·6H2O in the presence of the tetradentate ligand tris(2-pyridylmethyl)amine (TPyA) afford the dinuclear compound fac-{[FeIII(pzTp)(CN)2(μ-CN)] CuII(TPA)} ·Et2O·ClO4 (1) (pzTp = tetrakis(pyrazolyl)borate). The molecular structure was determined by single-crystal X-ray diffraction. In compound 1, the FeIII ion is coordinated by three cyanide carbon atoms and three nitrogen atoms of pzTp anions. Whereas, the CuII ion is surrounded by one cyanide nitrogen atom and four nitrogen atoms from the TPyA ligand. Magnetic measurements indicate the intramolecular ferromagnetic coupling is observed for compound 1, and it has S = 1 ground states.

本文言語英語
ページ(範囲)389-392
ページ数4
ジャーナルZeitschrift fur Anorganische und Allgemeine Chemie
635
2
DOI
出版ステータス出版済み - 2月 2009

!!!All Science Journal Classification (ASJC) codes

  • 無機化学

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「Synthesis, structure and magnetic properties of a cyano-bridged dinuclear compound fac-{[FeIII(pzTp)(CN)2(μ-CN)] Cu II(TPyA)}·Et2O·ClO4 (pzTp = tetrakis(pyrazolyl)borate)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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