Synthesis of Stereoselectively Functionalized Silacyclopentanes

Kazunobu Igawa; Akihiro Kuroo; Daisuke Yoshihiro; Yuki Yamanaka; Katsuhiko Tomooka

doi:10.1055/s-0036-1590826

Synthesis of Stereoselectively Functionalized Silacyclopentanes

Kazunobu Igawa, Akihiro Kuroo, Daisuke Yoshihiro, Yuki Yamanaka, Katsuhiko Tomooka

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

9 被引用数 (Scopus)

抄録

An efficient approach to a variety of chiral silacyclopentanes having silicon stereogenic center based on the stereospecific transformations of C4 carbon stereogenic center of silacyclopentenols by Mitsunobu reaction or Tsuji-Trost reaction has been developed. The thus obtained substitution products can be converted into novel silacyclopentane triols, amines, and carboxylic acids in stereospecific manner.

本文言語	英語
ページ（範囲）	2445-2448
ページ数	4
ジャーナル	Synlett
巻	28
号	18
DOI	https://doi.org/10.1055/s-0036-1590826
出版ステータス	出版済み - 11月 13 2017

!!!All Science Journal Classification (ASJC) codes

有機化学

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10.1055/s-0036-1590826

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author = "Kazunobu Igawa and Akihiro Kuroo and Daisuke Yoshihiro and Yuki Yamanaka and Katsuhiko Tomooka",

note = "Publisher Copyright: {\textcopyright} Georg Thieme Verlag Stuttgart.New York.",

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AU - Igawa, Kazunobu

AU - Kuroo, Akihiro

AU - Yoshihiro, Daisuke

AU - Yamanaka, Yuki

AU - Tomooka, Katsuhiko

PY - 2017/11/13

Y1 - 2017/11/13

N2 - An efficient approach to a variety of chiral silacyclopentanes having silicon stereogenic center based on the stereospecific transformations of C4 carbon stereogenic center of silacyclopentenols by Mitsunobu reaction or Tsuji-Trost reaction has been developed. The thus obtained substitution products can be converted into novel silacyclopentane triols, amines, and carboxylic acids in stereospecific manner.

AB - An efficient approach to a variety of chiral silacyclopentanes having silicon stereogenic center based on the stereospecific transformations of C4 carbon stereogenic center of silacyclopentenols by Mitsunobu reaction or Tsuji-Trost reaction has been developed. The thus obtained substitution products can be converted into novel silacyclopentane triols, amines, and carboxylic acids in stereospecific manner.

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Synthesis of Stereoselectively Functionalized Silacyclopentanes

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!!!All Science Journal Classification (ASJC) codes

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