Synthesis of monodispersed SnO2 nanocrystals and their remarkably high sensitivity to volatile organic compounds

Tetsuya Kida, Takayuki Doi, Kengo Shimanoe

研究成果: ジャーナルへの寄稿学術誌査読

125 被引用数 (Scopus)

抄録

In situ detection of volatile organic compounds (VOCs) in the atmosphere has become particularly important because of their detrimental effects on human health and the environment. To develop high-performance gas sensors capable of detecting VOCs in ppb concentrations, we prepared SnO2 nanocrystals by a liquid-phase synthesis method. Nearly monodispersed SnO2 nanocrystals (ca. 3.5 nm) were prepared by heating tin(IV) acetylacetonate in dibenzyl ether in the presence of oleic acid and oleylamine at 280 °C. The prepared nanocrystals exhibited high thermal stability against crystal growth, even at 600 °C, allowing for the fabrication of nanoparticulate gas-sensing films. The sensor device using the nanocrystals calcined at 600 °C exhibited significantly high sensor responses to VOCs such as ethanol, formaldehyde, and toluene at low ppm concentrations.

本文言語英語
ページ(範囲)2662-2667
ページ数6
ジャーナルChemistry of Materials
22
8
DOI
出版ステータス出版済み - 4月 27 2010

!!!All Science Journal Classification (ASJC) codes

  • 化学一般
  • 化学工学一般
  • 材料化学

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