Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant

Takeshi Yatabe; Takahiro Kikunaga; Takahiro Matsumoto; Hidetaka Nakai; Ki Seok Yoon; Seiji Ogo

doi:10.1246/cl.140376

Synthesis of aqueous-stable and water-soluble mononuclear nonheme Mn^V-Oxo complexes using H₂O₂as an oxidant

Takeshi Yatabe
, Takahiro Kikunaga
, Takahiro Matsumoto
, Hidetaka Nakai
, Ki Seok Yoon
, Seiji Ogo

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

4 被引用数 (Scopus)

抄録

We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.

本文言語	英語
ページ（範囲）	1380-1382
ページ数	3
ジャーナル	Chemistry Letters
巻	43
号	8
DOI	https://doi.org/10.1246/cl.140376
出版ステータス	出版済み - 2014

!!!All Science Journal Classification (ASJC) codes

化学一般

文献へのアクセス

10.1246/cl.140376

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引用スタイル

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title = "Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant",

abstract = "We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.",

author = "Takeshi Yatabe and Takahiro Kikunaga and Takahiro Matsumoto and Hidetaka Nakai and Yoon, \{Ki Seok\} and Seiji Ogo",

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AU - Yatabe, Takeshi

AU - Kikunaga, Takahiro

AU - Matsumoto, Takahiro

AU - Nakai, Hidetaka

AU - Yoon, Ki Seok

AU - Ogo, Seiji

PY - 2014

Y1 - 2014

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AB - We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.

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