Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

Mitsuo Ishikawa; Junnai Ikadai; Akinobu Naka; Joji Ohshita; Atsutaka Kunai; Kazunari Yoshizawa; Song Yun Kang; Tokio Yamabe

doi:10.1021/om000909q

Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

Mitsuo Ishikawa
, Junnai Ikadai
, Akinobu Naka
, Joji Ohshita
, Atsutaka Kunai
, Kazunari Yoshizawa
, Song Yun Kang
, Tokio Yamabe

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

19 被引用数 (Scopus)

抄録

The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

本文言語	英語
ページ（範囲）	1059-1061
ページ数	3
ジャーナル	Organometallics
巻	20
号	6
DOI	https://doi.org/10.1021/om000909q
出版ステータス	出版済み - 3月 19 2001
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

物理化学および理論化学
有機化学
無機化学

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10.1021/om000909q

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title = "Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene",

abstract = "The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.",

author = "Mitsuo Ishikawa and Junnai Ikadai and Akinobu Naka and Joji Ohshita and Atsutaka Kunai and Kazunari Yoshizawa and Kang, \{Song Yun\} and Tokio Yamabe",

year = "2001",

month = mar,

day = "19",

doi = "10.1021/om000909q",

language = "English",

volume = "20",

pages = "1059--1061",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

AU - Ishikawa, Mitsuo

AU - Ikadai, Junnai

AU - Naka, Akinobu

AU - Ohshita, Joji

AU - Kunai, Atsutaka

AU - Yoshizawa, Kazunari

AU - Kang, Song Yun

AU - Yamabe, Tokio

PY - 2001/3/19

Y1 - 2001/3/19

N2 - The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

AB - The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

UR - https://www.scopus.com/pages/publications/0035911990

UR - https://www.scopus.com/pages/publications/0035911990#tab=citedBy

U2 - 10.1021/om000909q

DO - 10.1021/om000909q

M3 - Article

AN - SCOPUS:0035911990

SN - 0276-7333

VL - 20

SP - 1059

EP - 1061

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

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!!!All Science Journal Classification (ASJC) codes

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