Synthesis and Stereochemical Analysis of Ten-membered Diallylic Nitrogen Cycle and Its Pt-Complex

Jun Ichi Hayashi; Masaki Suzuki; Maki Shimada; Yuuya Kawasaki; Kazunobu Igawa; Katsuhiko Tomooka

doi:10.1246/cl.220143

Synthesis and Stereochemical Analysis of Ten-membered Diallylic Nitrogen Cycle and Its Pt-Complex

Jun Ichi Hayashi, Masaki Suzuki, Maki Shimada, Yuuya Kawasaki, Kazunobu Igawa, Katsuhiko Tomooka

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

1 被引用数 (Scopus)

抄録

Newly synthesized ten-membered diallylic nitrogen cycle, having E- and Z-alkene moieties, shows labile planar-chirality at ambient temperature. VT-NMR experiments revealed the detail of the stereochemical behavior of interconversion of the enantiomers and diastereomers. In sharp contrast, Pt-complex of the nitrogen cycle have more stable planar chirality, and the enantiomers of the Pt-complex were isolated by HPLC using a chiral stationary phase.

本文言語	英語
ページ（範囲）	636-638
ページ数	3
ジャーナル	Chemistry Letters
巻	51
号	6
DOI	https://doi.org/10.1246/cl.220143
出版ステータス	出版済み - 6月 2022

!!!All Science Journal Classification (ASJC) codes

化学一般

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10.1246/cl.220143

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title = "Synthesis and Stereochemical Analysis of Ten-membered Diallylic Nitrogen Cycle and Its Pt-Complex",

abstract = "Newly synthesized ten-membered diallylic nitrogen cycle, having E- and Z-alkene moieties, shows labile planar-chirality at ambient temperature. VT-NMR experiments revealed the detail of the stereochemical behavior of interconversion of the enantiomers and diastereomers. In sharp contrast, Pt-complex of the nitrogen cycle have more stable planar chirality, and the enantiomers of the Pt-complex were isolated by HPLC using a chiral stationary phase.",

author = "Hayashi, {Jun Ichi} and Masaki Suzuki and Maki Shimada and Yuuya Kawasaki and Kazunobu Igawa and Katsuhiko Tomooka",

note = "Publisher Copyright: {\textcopyright} 2022 The Chemical Society of Japan.",

year = "2022",

month = jun,

doi = "10.1246/cl.220143",

language = "English",

volume = "51",

pages = "636--638",

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T1 - Synthesis and Stereochemical Analysis of Ten-membered Diallylic Nitrogen Cycle and Its Pt-Complex

AU - Hayashi, Jun Ichi

AU - Suzuki, Masaki

AU - Shimada, Maki

AU - Kawasaki, Yuuya

AU - Igawa, Kazunobu

AU - Tomooka, Katsuhiko

PY - 2022/6

Y1 - 2022/6

N2 - Newly synthesized ten-membered diallylic nitrogen cycle, having E- and Z-alkene moieties, shows labile planar-chirality at ambient temperature. VT-NMR experiments revealed the detail of the stereochemical behavior of interconversion of the enantiomers and diastereomers. In sharp contrast, Pt-complex of the nitrogen cycle have more stable planar chirality, and the enantiomers of the Pt-complex were isolated by HPLC using a chiral stationary phase.

AB - Newly synthesized ten-membered diallylic nitrogen cycle, having E- and Z-alkene moieties, shows labile planar-chirality at ambient temperature. VT-NMR experiments revealed the detail of the stereochemical behavior of interconversion of the enantiomers and diastereomers. In sharp contrast, Pt-complex of the nitrogen cycle have more stable planar chirality, and the enantiomers of the Pt-complex were isolated by HPLC using a chiral stationary phase.

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DO - 10.1246/cl.220143

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VL - 51

SP - 636

EP - 638

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

Synthesis and Stereochemical Analysis of Ten-membered Diallylic Nitrogen Cycle and Its Pt-Complex

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!!!All Science Journal Classification (ASJC) codes

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