Swelling behavior of poly(sodium acrylate) gels crosslinked by aluminum ions

Tomofumi Harada, Hiroaki Sato, Yumiko Hirashima, Keiji Igarashi, Atsushi Suzuki, Motoaki Goto, Naohisa Kawamura, Masayuki Tokita

研究成果: ジャーナルへの寄稿学術誌査読

11 被引用数 (Scopus)

抄録

The cylindrical poly(sodium acrylate) gel (SA gel) was synthesized in the glass capillary using aluminum ions as the crosslinker. The swelling ratio of the gel was measured after the repeated exchange of solvent (distilled deionized water, about pH 5.8). The gel exhibited two relaxation processes; at first the gel swells rapidly as exchange of water (the swelling process), then shrinks very slowly (the shrinking process). In order to reveal the microscopic structural change (especially, the formation of hydrogen bonding) by water exchange, attenuated total refraction (ATR) Fourier transform infrared (FT-IR) spectroscopy was applied to the gels with different swelling ratio. The IR absorption peaks of the gel were assigned based on those of poly(sodium acrylate) aqueous solutions at different pH. On the swelling process, the carboxyl groups were gradually protonated, and the intermolecular hydrogen bonding started to form in the gel with maximum swelling ratio. On the shrinking process, the formation of hydrogen bonding gradually increased with long-time repeated water exchange which resulted in the shrinkage of the gel. Effects of the repeated water exchange on the swelling behavior were discussed in terms of the exchange of counter ions and the formation of hydrogen bonding.

本文言語英語
ページ(範囲)209-212
ページ数4
ジャーナルColloids and Surfaces B: Biointerfaces
38
3-4 SPEC. ISS.
DOI
出版ステータス出版済み - 11月 15 2004

!!!All Science Journal Classification (ASJC) codes

  • バイオテクノロジー
  • 表面および界面
  • 物理化学および理論化学
  • コロイド化学および表面化学

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