Stereospecific polymerization with PMMA binding peptide

Kun Zhang, Yusuke Hosaka, Hisao Matsuno, Takeshi Serizawa

研究成果: 会議への寄与タイプ学会誌査読

抄録

Recently, we have firstly reported a 7-motif peptide (Glu-Leu-Trp-Arg-Pro- Thr-Arg) that specifically binds to isotactic (it) poly (methyl methacrylate) (PMMA). Based on the obtained achievements, the peptide was used as template to prepare PMMA with high isotacticity through free radical polymerization at the presence of (i-PrOCOO)2, KPS-TEMED or BPO-DMA as initiator. The results of NMR measurements showed that the tacticity of obtained PMMA was almost same as that of conventional PMMA (mm:mr:rr = 3:33:64). It seemed that the concentration of peptide and the polymerization temperature did not have distinct effect on the tacticity of obtained PMMA and the solvent was a key factor to get PMMA with high isotacticity.

本文言語英語
ページ716
ページ数1
出版ステータス出版済み - 2006
外部発表はい
イベント55th SPSJ Annual Meeting - Nagoya, 日本
継続期間: 5月 24 20065月 26 2006

その他

その他55th SPSJ Annual Meeting
国/地域日本
CityNagoya
Period5/24/065/26/06

!!!All Science Journal Classification (ASJC) codes

  • 工学一般

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