Stepwise synthesis of fullerene cyclopentadienide R5C60- and indenide R3C60-. An approach to fully unsymmetrically substituted derivatives

Masaya Sawamura; Motoki Toganoh; Kazuhiro Suzuki; Atsushi Hirai; Hitoshi Iikura; Eiichi Nakamura

doi:10.1021/ol005993k

Stepwise synthesis of fullerene cyclopentadienide R₅C₆₀^- and indenide R₃C₆₀^-. An approach to fully unsymmetrically substituted derivatives

Masaya Sawamura, Motoki Toganoh, Kazuhiro Suzuki, Atsushi Hirai, Hitoshi Iikura, Eiichi Nakamura

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

44 被引用数 (Scopus)

抄録

(Equation presented) Fullerene cyclopentadienide (PhCH₂)₂Ph₃C₆₀^- and indenide (PhCH₂)₂PhC₆₀^-, each bearing two different organic groups, were efficiently synthesized through regioselective reactions of 1,4-(PhCH₂)₂C₆₀ with an organocopper reagent (PhMgBr/CuBr-SMe₂) or a Grignard reagent (PhMgBr) followed by deprotonation with KO^tBu.

本文言語	英語
ページ（範囲）	1919-1921
ページ数	3
ジャーナル	Organic letters
巻	2
号	13
DOI	https://doi.org/10.1021/ol005993k
出版ステータス	出版済み - 6月 29 2000
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

生化学
物理化学および理論化学
有機化学

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10.1021/ol005993k

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引用スタイル

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abstract = "(Equation presented) Fullerene cyclopentadienide (PhCH2)2Ph3C60- and indenide (PhCH2)2PhC60-, each bearing two different organic groups, were efficiently synthesized through regioselective reactions of 1,4-(PhCH2)2C60 with an organocopper reagent (PhMgBr/CuBr-SMe2) or a Grignard reagent (PhMgBr) followed by deprotonation with KOtBu.",

author = "Masaya Sawamura and Motoki Toganoh and Kazuhiro Suzuki and Atsushi Hirai and Hitoshi Iikura and Eiichi Nakamura",

year = "2000",

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doi = "10.1021/ol005993k",

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T1 - Stepwise synthesis of fullerene cyclopentadienide R5C60- and indenide R3C60-. An approach to fully unsymmetrically substituted derivatives

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AU - Toganoh, Motoki

AU - Suzuki, Kazuhiro

AU - Hirai, Atsushi

AU - Iikura, Hitoshi

AU - Nakamura, Eiichi

PY - 2000/6/29

Y1 - 2000/6/29

N2 - (Equation presented) Fullerene cyclopentadienide (PhCH2)2Ph3C60- and indenide (PhCH2)2PhC60-, each bearing two different organic groups, were efficiently synthesized through regioselective reactions of 1,4-(PhCH2)2C60 with an organocopper reagent (PhMgBr/CuBr-SMe2) or a Grignard reagent (PhMgBr) followed by deprotonation with KOtBu.

AB - (Equation presented) Fullerene cyclopentadienide (PhCH2)2Ph3C60- and indenide (PhCH2)2PhC60-, each bearing two different organic groups, were efficiently synthesized through regioselective reactions of 1,4-(PhCH2)2C60 with an organocopper reagent (PhMgBr/CuBr-SMe2) or a Grignard reagent (PhMgBr) followed by deprotonation with KOtBu.

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