Stepwise synthesis and magnetic control of trimetallic magnets [Co 2Ln(L)2(H2O)4][Cr(CN)6] ·nH2O (Ln = La, Gd; H2L = 2,6-di(acetoacetyl) pyridine) with 3-D pillared-layer structure

Takuya Shiga; Hisashi Ökawa; Susumu Kitagawa; Masaaki Ohba

doi:10.1021/ja066434x

Stepwise synthesis and magnetic control of trimetallic magnets [Co ₂Ln(L)₂(H₂O)4][Cr(CN)₆] ·nH₂O (Ln = La, Gd; H₂L = 2,6-di(acetoacetyl) pyridine) with 3-D pillared-layer structure

Takuya Shiga, Hisashi Ökawa, Susumu Kitagawa, Masaaki Ohba

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

139 被引用数 (Scopus)

抄録

Integration of mononuclear [Cr(CN)₆]^3- and preorganized trinuclear [Co₂Ln(L)₂]³⁺ complexes provides novel trimetallic magnets having a 3-D pillared-layer framework with an alternate array of 2-D layer extended by Cr(III)?CN?Co(II) linkages and Ln(III) ion. The overall magnetic nature can be systematically controlled by Ln(III) ions inserted between the 2-D ferromagnetic layers.

本文言語	英語
ページ（範囲）	16426-16427
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	128
号	51
DOI	https://doi.org/10.1021/ja066434x
出版ステータス	出版済み - 12月 27 2006
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

触媒
化学 (全般)
生化学
コロイド化学および表面化学

文献へのアクセス

10.1021/ja066434x

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「Stepwise synthesis and magnetic control of trimetallic magnets [Co ₂Ln(L)₂(H₂O)4][Cr(CN)₆] ·nH₂O (Ln = La, Gd; H₂L = 2,6-di(acetoacetyl) pyridine) with 3-D pillared-layer structure」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

Stepwise synthesis and magnetic control of trimetallic magnets [Co ₂Ln(L)₂(H₂O)4][Cr(CN)₆] ·nH₂O (Ln = La, Gd; H₂L = 2,6-di(acetoacetyl) pyridine) with 3-D pillared-layer structure. / Shiga, Takuya; Ökawa, Hisashi; Kitagawa, Susumu その他.
In: Journal of the American Chemical Society, Vol. 128, No. 51, 27.12.2006, p. 16426-16427.

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

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title = "Stepwise synthesis and magnetic control of trimetallic magnets [Co 2Ln(L)2(H2O)4][Cr(CN)6] ·nH2O (Ln = La, Gd; H2L = 2,6-di(acetoacetyl) pyridine) with 3-D pillared-layer structure",

abstract = "Integration of mononuclear [Cr(CN)6]3- and preorganized trinuclear [Co2Ln(L)2]3+ complexes provides novel trimetallic magnets having a 3-D pillared-layer framework with an alternate array of 2-D layer extended by Cr(III)?CN?Co(II) linkages and Ln(III) ion. The overall magnetic nature can be systematically controlled by Ln(III) ions inserted between the 2-D ferromagnetic layers.",

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