Stable π Radical from a Contracted Doubly N-Confused Hexaphyrin by Double Palladium Metalation

Yutaka Hisamune; Keiichi Nishimura; Koji Isakari; Masatoshi Ishida; Shigeki Mori; Satoru Karasawa; Tatsuhisa Kato; Sangsu Lee; Dongho Kim; Hiroyuki Furuta

doi:10.1002/anie.201502285

Stable π Radical from a Contracted Doubly N-Confused Hexaphyrin by Double Palladium Metalation

Yutaka Hisamune, Keiichi Nishimura, Koji Isakari, Masatoshi Ishida, Shigeki Mori, Satoru Karasawa, Tatsuhisa Kato, Sangsu Lee, Dongho Kim, Hiroyuki Furuta

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

45 被引用数 (Scopus)

抄録

A contracted doubly N-confused dioxohexaphyrin derivative served as a dinucleating metal ligand for unsymmetrical coordination. The complexation of two palladium(II) cations led to the formation of π-radical species that were persistent in atmospheric air in the presence of moisture. Effective delocalization of an unpaired electron over the hexaphyrin backbone could contribute to the distinct chemical stability.

本文言語	英語
ページ（範囲）	7323-7327
ページ数	5
ジャーナル	Angewandte Chemie - International Edition
巻	54
号	25
DOI	https://doi.org/10.1002/anie.201502285
出版ステータス	出版済み - 6月 1 2015

!!!All Science Journal Classification (ASJC) codes

触媒
化学 (全般)

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abstract = "A contracted doubly N-confused dioxohexaphyrin derivative served as a dinucleating metal ligand for unsymmetrical coordination. The complexation of two palladium(II) cations led to the formation of π-radical species that were persistent in atmospheric air in the presence of moisture. Effective delocalization of an unpaired electron over the hexaphyrin backbone could contribute to the distinct chemical stability.",

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AU - Hisamune, Yutaka

AU - Nishimura, Keiichi

AU - Isakari, Koji

AU - Ishida, Masatoshi

AU - Mori, Shigeki

AU - Karasawa, Satoru

AU - Kato, Tatsuhisa

AU - Lee, Sangsu

AU - Kim, Dongho

AU - Furuta, Hiroyuki

PY - 2015/6/1

Y1 - 2015/6/1

N2 - A contracted doubly N-confused dioxohexaphyrin derivative served as a dinucleating metal ligand for unsymmetrical coordination. The complexation of two palladium(II) cations led to the formation of π-radical species that were persistent in atmospheric air in the presence of moisture. Effective delocalization of an unpaired electron over the hexaphyrin backbone could contribute to the distinct chemical stability.

AB - A contracted doubly N-confused dioxohexaphyrin derivative served as a dinucleating metal ligand for unsymmetrical coordination. The complexation of two palladium(II) cations led to the formation of π-radical species that were persistent in atmospheric air in the presence of moisture. Effective delocalization of an unpaired electron over the hexaphyrin backbone could contribute to the distinct chemical stability.

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Stable π Radical from a Contracted Doubly N-Confused Hexaphyrin by Double Palladium Metalation

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!!!All Science Journal Classification (ASJC) codes

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