Sequential ruthenium-catalyzed hydroamination and rhenium-catalyzed C-H bond activation leading to indene derivatives

Yoichiro Kuninobu; Yuta Nishina; Kazuhiko Takai

doi:10.1021/ol0611292

Sequential ruthenium-catalyzed hydroamination and rhenium-catalyzed C-H bond activation leading to indene derivatives

Yoichiro Kuninobu
, Yuta Nishina
, Kazuhiko Takai

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

43 被引用数 (Scopus)

抄録

Formal [3+2] annulation of arylacetylenes and α,β-unsaturated carbonyl compounds is achieved in a one-pot reaction by successive treatment of the acetylenes with aniline and a catalytic amount of Ru₃(CO) ₁₂ and NH₄PF₆ and C-H bond activation catalyzed by [ReBr(CO)₃(thf)]₂. The result suggests that the second rhenium-catalyzed indene formation is not disturbed by the first catalyst system.

本文言語	英語
ページ（範囲）	2891-2893
ページ数	3
ジャーナル	Organic letters
巻	8
号	13
DOI	https://doi.org/10.1021/ol0611292
出版ステータス	出版済み - 6月 22 2006
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

生化学
物理化学および理論化学
有機化学

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10.1021/ol0611292

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abstract = "Formal [3+2] annulation of arylacetylenes and α,β-unsaturated carbonyl compounds is achieved in a one-pot reaction by successive treatment of the acetylenes with aniline and a catalytic amount of Ru3(CO) 12 and NH4PF6 and C-H bond activation catalyzed by [ReBr(CO)3(thf)]2. The result suggests that the second rhenium-catalyzed indene formation is not disturbed by the first catalyst system.",

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year = "2006",

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T1 - Sequential ruthenium-catalyzed hydroamination and rhenium-catalyzed C-H bond activation leading to indene derivatives

AU - Kuninobu, Yoichiro

AU - Nishina, Yuta

AU - Takai, Kazuhiko

PY - 2006/6/22

Y1 - 2006/6/22

N2 - Formal [3+2] annulation of arylacetylenes and α,β-unsaturated carbonyl compounds is achieved in a one-pot reaction by successive treatment of the acetylenes with aniline and a catalytic amount of Ru3(CO) 12 and NH4PF6 and C-H bond activation catalyzed by [ReBr(CO)3(thf)]2. The result suggests that the second rhenium-catalyzed indene formation is not disturbed by the first catalyst system.

AB - Formal [3+2] annulation of arylacetylenes and α,β-unsaturated carbonyl compounds is achieved in a one-pot reaction by successive treatment of the acetylenes with aniline and a catalytic amount of Ru3(CO) 12 and NH4PF6 and C-H bond activation catalyzed by [ReBr(CO)3(thf)]2. The result suggests that the second rhenium-catalyzed indene formation is not disturbed by the first catalyst system.

UR - https://www.scopus.com/pages/publications/33746141335

UR - https://www.scopus.com/pages/publications/33746141335#tab=citedBy

U2 - 10.1021/ol0611292

DO - 10.1021/ol0611292

M3 - Article

C2 - 16774283

AN - SCOPUS:33746141335

SN - 1523-7060

VL - 8

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JO - Organic letters

JF - Organic letters

IS - 13

ER -

Sequential ruthenium-catalyzed hydroamination and rhenium-catalyzed C-H bond activation leading to indene derivatives

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!!!All Science Journal Classification (ASJC) codes

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