Selective hydroxylation of cyclohexene over Fe-bipyridine complexes encapsulated into Y-type zeolite under environment-friendly conditions

Syuhei Yamaguchi; Tomohiro Fukura; Keiko Takiguchi; Chiharu Fujita; Maiko Nishibori; Yasutake Teraoka; Hidenori Yahiro

doi:10.1016/j.cattod.2014.07.038

Selective hydroxylation of cyclohexene over Fe-bipyridine complexes encapsulated into Y-type zeolite under environment-friendly conditions

Syuhei Yamaguchi, Tomohiro Fukura, Keiko Takiguchi, Chiharu Fujita, Maiko Nishibori, Yasutake Teraoka, Hidenori Yahiro

機能材料設計学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

19 被引用数 (Scopus)

抄録

Fe-bipyridine complexes encapsulated into Na-Y ([Fe(bpy)₃]²⁺@Y) were prepared and their catalytic activities for oxidation of cyclohexene with hydrogen peroxide in CH₃CN and H₂O solvents were investigated. The prepared [Fe(bpy)₃]²⁺@Y was characterized by several methods and it was found that slightly distorted or compressed [Fe(bpy)₃]²⁺ ions were formed within supercages of Y-type zeolite. [Fe(bpy)₃]²⁺@Y catalyst exhibited both higher activity and higher selectivity to 2-cyclohexen-1-ol in water solvent than another Fe catalysts. In addition, the selective hydroxylation of cyclohexene to 2-cyclohexen-1-ol with molecular oxygen was successfully achieved for [Fe(bpy)₃]²⁺@Y catalyst.

本文言語	英語
ページ（範囲）	261-267
ページ数	7
ジャーナル	Catalysis Today
巻	242
号	PB
DOI	https://doi.org/10.1016/j.cattod.2014.07.038
出版ステータス	出版済み - 3月 15 2015

!!!All Science Journal Classification (ASJC) codes

触媒
化学一般

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10.1016/j.cattod.2014.07.038

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引用スタイル

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title = "Selective hydroxylation of cyclohexene over Fe-bipyridine complexes encapsulated into Y-type zeolite under environment-friendly conditions",

abstract = "Fe-bipyridine complexes encapsulated into Na-Y ([Fe(bpy)3]2+@Y) were prepared and their catalytic activities for oxidation of cyclohexene with hydrogen peroxide in CH3CN and H2O solvents were investigated. The prepared [Fe(bpy)3]2+@Y was characterized by several methods and it was found that slightly distorted or compressed [Fe(bpy)3]2+ ions were formed within supercages of Y-type zeolite. [Fe(bpy)3]2+@Y catalyst exhibited both higher activity and higher selectivity to 2-cyclohexen-1-ol in water solvent than another Fe catalysts. In addition, the selective hydroxylation of cyclohexene to 2-cyclohexen-1-ol with molecular oxygen was successfully achieved for [Fe(bpy)3]2+@Y catalyst.",

author = "Syuhei Yamaguchi and Tomohiro Fukura and Keiko Takiguchi and Chiharu Fujita and Maiko Nishibori and Yasutake Teraoka and Hidenori Yahiro",

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T1 - Selective hydroxylation of cyclohexene over Fe-bipyridine complexes encapsulated into Y-type zeolite under environment-friendly conditions

AU - Yamaguchi, Syuhei

AU - Fukura, Tomohiro

AU - Takiguchi, Keiko

AU - Fujita, Chiharu

AU - Nishibori, Maiko

AU - Teraoka, Yasutake

AU - Yahiro, Hidenori

PY - 2015/3/15

Y1 - 2015/3/15

N2 - Fe-bipyridine complexes encapsulated into Na-Y ([Fe(bpy)3]2+@Y) were prepared and their catalytic activities for oxidation of cyclohexene with hydrogen peroxide in CH3CN and H2O solvents were investigated. The prepared [Fe(bpy)3]2+@Y was characterized by several methods and it was found that slightly distorted or compressed [Fe(bpy)3]2+ ions were formed within supercages of Y-type zeolite. [Fe(bpy)3]2+@Y catalyst exhibited both higher activity and higher selectivity to 2-cyclohexen-1-ol in water solvent than another Fe catalysts. In addition, the selective hydroxylation of cyclohexene to 2-cyclohexen-1-ol with molecular oxygen was successfully achieved for [Fe(bpy)3]2+@Y catalyst.

AB - Fe-bipyridine complexes encapsulated into Na-Y ([Fe(bpy)3]2+@Y) were prepared and their catalytic activities for oxidation of cyclohexene with hydrogen peroxide in CH3CN and H2O solvents were investigated. The prepared [Fe(bpy)3]2+@Y was characterized by several methods and it was found that slightly distorted or compressed [Fe(bpy)3]2+ ions were formed within supercages of Y-type zeolite. [Fe(bpy)3]2+@Y catalyst exhibited both higher activity and higher selectivity to 2-cyclohexen-1-ol in water solvent than another Fe catalysts. In addition, the selective hydroxylation of cyclohexene to 2-cyclohexen-1-ol with molecular oxygen was successfully achieved for [Fe(bpy)3]2+@Y catalyst.

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