Sedimentary PGE signatures in the Late Triassic ejecta deposits from Japan: Implications for the identification of impactor

Positive platinum group element (PGE) concentration and negative Os isotope anomalies reported from a claystone layer in the Upper Triassic bedded chert succession of the Sakahogi section, Mino Belt, central Japan, are thought to have been derived from an impact event. Stratigraphic variations and concentrations of PGE were examined in the Sakahogi section to determine the type of the impactor. Upper Triassic claystone layers, where PGE anomalies have been newly discovered in bedded chert successions in southwest Japan, were also examined. These include (i) the Unuma section in the Inuyama area, Mino Belt; (ii) the Hisuikyo section in the Kamiaso area, Mino Belt; and (iii) the Enoura section in the Tsukumi area, Chichibu Belt. Radiolarian and conodont biostratigraphic data indicate that these claystone layers are of upper-middle Norian age. Reconstruction of bedded chert in these sections suggests that they originate from open-ocean pelagic deep-sea sediments deposited in the Panthalassa Ocean.The relatively flat CI chondrite-normalized patterns of the least mobile PGEs (Ir, Ru, and Rh) and the Ru/Ir ratio determined by linear regression analysis suggest that a chondritic impactor is the source of the PGE anomalies preserved in claystone samples from the study sections. Although Ru/Ir ratios cannot conclusively distinguish chondrites from iron meteorites, the Cr/Ir ratios of the claystone layers range from 10⁴ to 10⁵, clearly indicating contribution from chondritic materials. The chondritic impactor of the suggested size (3.3-7.8km in diameter) implies that a large amount of debris and/or climatically active gasses (e.g., sulfur oxides) would have been released from the impactor, which would have had a marked effect on the environment.