Rhenium-catalyzed regioselective alkylation of phenols

Yoichiro Kuninobu; Takashi Matsuki; Kazuhiko Takai

doi:10.1021/ja904360k

Rhenium-catalyzed regioselective alkylation of phenols

Yoichiro Kuninobu, Takashi Matsuki, Kazuhiko Takai

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

83 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Treatment of phenol derivatives with terminal alkenes in the presence of a catalytic amount of a rhenium complex, Re ₂(CO)₁₀, gave monoalkylated phenol derivatives in good to excellent yields. This reaction proceeds at the ortho- or para-position of phenols regioselectively.

本文言語	英語
ページ（範囲）	9914-9915
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	131
号	29
DOI	https://doi.org/10.1021/ja904360k
出版ステータス	出版済み - 7月 29 2009
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

触媒
化学 (全般)
生化学
コロイド化学および表面化学

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10.1021/ja904360k

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title = "Rhenium-catalyzed regioselective alkylation of phenols",

abstract = "(Chemical Equation Presented) Treatment of phenol derivatives with terminal alkenes in the presence of a catalytic amount of a rhenium complex, Re 2(CO)10, gave monoalkylated phenol derivatives in good to excellent yields. This reaction proceeds at the ortho- or para-position of phenols regioselectively.",

author = "Yoichiro Kuninobu and Takashi Matsuki and Kazuhiko Takai",

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N2 - (Chemical Equation Presented) Treatment of phenol derivatives with terminal alkenes in the presence of a catalytic amount of a rhenium complex, Re 2(CO)10, gave monoalkylated phenol derivatives in good to excellent yields. This reaction proceeds at the ortho- or para-position of phenols regioselectively.

AB - (Chemical Equation Presented) Treatment of phenol derivatives with terminal alkenes in the presence of a catalytic amount of a rhenium complex, Re 2(CO)10, gave monoalkylated phenol derivatives in good to excellent yields. This reaction proceeds at the ortho- or para-position of phenols regioselectively.

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Rhenium-catalyzed regioselective alkylation of phenols

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!!!All Science Journal Classification (ASJC) codes

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