Rhenium-catalyzed insertion of terminal acetylenes into a C-H bond of active methylene compounds

Yoichiro Kuninobu; Atsushi Kawata; Kazuhiko Takai

doi:10.1021/ol0515208

Rhenium-catalyzed insertion of terminal acetylenes into a C-H bond of active methylene compounds

Yoichiro Kuninobu
, Atsushi Kawata
, Kazuhiko Takai

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

104 被引用数 (Scopus)

抄録

(Chemical Equation Presented) A rhenium complex, [ReBr(CO) ₃(thf)]₂, catalyzed the intermolecular reactions of 1,3-dicarbonyl compounds with terminal acetylenes and gave the corresponding alkenyl derivatives in excellent yields. These reactions could apply to an intramolecular version and gave the corresponding cyclic compounds quantitatively.

本文言語	英語
ページ（範囲）	4823-4825
ページ数	3
ジャーナル	Organic letters
巻	7
号	22
DOI	https://doi.org/10.1021/ol0515208
出版ステータス	出版済み - 10月 27 2005
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

生化学
物理化学および理論化学
有機化学

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10.1021/ol0515208

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title = "Rhenium-catalyzed insertion of terminal acetylenes into a C-H bond of active methylene compounds",

abstract = "(Chemical Equation Presented) A rhenium complex, [ReBr(CO) 3(thf)]2, catalyzed the intermolecular reactions of 1,3-dicarbonyl compounds with terminal acetylenes and gave the corresponding alkenyl derivatives in excellent yields. These reactions could apply to an intramolecular version and gave the corresponding cyclic compounds quantitatively.",

author = "Yoichiro Kuninobu and Atsushi Kawata and Kazuhiko Takai",

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T1 - Rhenium-catalyzed insertion of terminal acetylenes into a C-H bond of active methylene compounds

AU - Kuninobu, Yoichiro

AU - Kawata, Atsushi

AU - Takai, Kazuhiko

PY - 2005/10/27

Y1 - 2005/10/27

N2 - (Chemical Equation Presented) A rhenium complex, [ReBr(CO) 3(thf)]2, catalyzed the intermolecular reactions of 1,3-dicarbonyl compounds with terminal acetylenes and gave the corresponding alkenyl derivatives in excellent yields. These reactions could apply to an intramolecular version and gave the corresponding cyclic compounds quantitatively.

AB - (Chemical Equation Presented) A rhenium complex, [ReBr(CO) 3(thf)]2, catalyzed the intermolecular reactions of 1,3-dicarbonyl compounds with terminal acetylenes and gave the corresponding alkenyl derivatives in excellent yields. These reactions could apply to an intramolecular version and gave the corresponding cyclic compounds quantitatively.

UR - https://www.scopus.com/pages/publications/27644479913

UR - https://www.scopus.com/pages/publications/27644479913#tab=citedBy

U2 - 10.1021/ol0515208

DO - 10.1021/ol0515208

M3 - Article

C2 - 16235898

AN - SCOPUS:27644479913

SN - 1523-7060

VL - 7

SP - 4823

EP - 4825

JO - Organic letters

JF - Organic letters

IS - 22

ER -

Rhenium-catalyzed insertion of terminal acetylenes into a C-H bond of active methylene compounds

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!!!All Science Journal Classification (ASJC) codes

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