Redox gradations in ruthenium porphycene complexes and the porphyrin analogs: Axial and macrocyclic ligand effects

Toru Okawara; Masaaki Abe; Hisashi Shimakoshi; Yoshio Hisaeda

doi:10.1246/cl.2008.906

Redox gradations in ruthenium porphycene complexes and the porphyrin analogs: Axial and macrocyclic ligand effects

Toru Okawara
, Masaaki Abe
, Hisashi Shimakoshi
, Yoshio Hisaeda

連携融合理工学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

15 被引用数 (Scopus)

抄録

This paper reports synthesis and electrochemistry of six-coordinate ruthenium porphyrin isomers including six novel porphycene complexes with substituted pyridines in the axial positions, in which redox potential control of reversible Ru^II/Ru^III processes is successfully achieved over a 0.7-V potential region by varying the axial ligands and tetrapyrrole ligand structure and substituents.

本文言語	英語
ページ（範囲）	906-907
ページ数	2
ジャーナル	Chemistry Letters
巻	37
号	9
DOI	https://doi.org/10.1246/cl.2008.906
出版ステータス	出版済み - 9月 5 2008

!!!All Science Journal Classification (ASJC) codes

化学一般

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10.1246/cl.2008.906

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abstract = "This paper reports synthesis and electrochemistry of six-coordinate ruthenium porphyrin isomers including six novel porphycene complexes with substituted pyridines in the axial positions, in which redox potential control of reversible RuII/RuIII processes is successfully achieved over a 0.7-V potential region by varying the axial ligands and tetrapyrrole ligand structure and substituents.",

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T2 - Axial and macrocyclic ligand effects

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AU - Abe, Masaaki

AU - Shimakoshi, Hisashi

AU - Hisaeda, Yoshio

PY - 2008/9/5

Y1 - 2008/9/5

N2 - This paper reports synthesis and electrochemistry of six-coordinate ruthenium porphyrin isomers including six novel porphycene complexes with substituted pyridines in the axial positions, in which redox potential control of reversible RuII/RuIII processes is successfully achieved over a 0.7-V potential region by varying the axial ligands and tetrapyrrole ligand structure and substituents.

AB - This paper reports synthesis and electrochemistry of six-coordinate ruthenium porphyrin isomers including six novel porphycene complexes with substituted pyridines in the axial positions, in which redox potential control of reversible RuII/RuIII processes is successfully achieved over a 0.7-V potential region by varying the axial ligands and tetrapyrrole ligand structure and substituents.

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DO - 10.1246/cl.2008.906

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SN - 0366-7022

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JO - Chemistry Letters

JF - Chemistry Letters

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Redox gradations in ruthenium porphycene complexes and the porphyrin analogs: Axial and macrocyclic ligand effects

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!!!All Science Journal Classification (ASJC) codes

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