Pressure response of three-dimensional cyanide-bridged bimetallic magnets

Masaaki Ohba, Wakako Kaneko, Susumu Kitagawa, Takuho Maeda, Masaki Mito

研究成果: ジャーナルへの寄稿学術誌査読

91 被引用数 (Scopus)

抄録

Effects of pressure on the structures and magnetic properties of three types of 3-D cyanide-bridged bimetallic coordination polymer magnets, Mn IICrIII ferrimagnet [Mn(en)]3[Cr(CN) 6]2·4H2O (1; en = ethylenediamine), NiIICrIII ferromagnet [Ni(dipn)]3[Cr(CN) 6]2·3H2O (2; dipn = N,N-di(3- aminopropyl)amine), and NiIIFeIII ferromagnet [Ni(dipn)]2[Ni(dipn)(H2O)][Fe(CN)6] 2·11H2O (3), were systematically examined under hydrostatic pressure up to 19.8 GPa using a piston-cylinder-type pressure cell and a diamond anvil cell. The ferrimagnet 1 showed the reversible crystalline-to-amorphous-like phase change, and the magnetic phase transition temperature (TC) was reversibly changed from 69 K at 0 GPa to 126 K at 4.7 GPa. At higher pressure, the net magnetization was suppressed with increasing pressure, and the magnetic state at 19.8 GPa was assumed to be paramagnetic. The initial ferrimagnetic phase of 1 was not recovered after releasing the pressure from 19.8 GPa. The magnetic phase of 2 was reversibly converted between ferromagnetic and paramagnetic-like phase in the range 0 ≤ P ≤ 4.7 GPa while maintaining its crystallinity. The porous ferromagnet 3 was easily amorphized and irreversibly lost the ferromagnetic phase under low pressure (P ≤ 1.0 GPa). The flexible cyanide-bridged magnetic frameworks demonstrate well the pressure response as a reflection of differences in the magnetic structure and the framework strength in the GPa range.

本文言語英語
ページ(範囲)4475-4484
ページ数10
ジャーナルJournal of the American Chemical Society
130
13
DOI
出版ステータス出版済み - 4月 2 2008
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学一般
  • 生化学
  • コロイド化学および表面化学

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