Pressure-induced valence transition and characteristic electronic states in EuRh2Si2

Fuminori Honda, Keigo Okauchi, Ai Nakamura, Dexin Li, Dai Aoki, Hiromu Akamine, Yousuke Ashitomi, Masato Hedo, Takao Nakama, Yoshichika Onuki

研究成果: ジャーナルへの寄稿学術誌査読

31 被引用数 (Scopus)


EuRh2Si2 is well known to show a valence transition at a pressure of about 1 GPa from a Eu-divalent (antiferromagnetic) state to a nearly Eu-trivalent (paramagnetic) state, which was clarified using polycrystalline samples. We have succeeded in growing single crystals of EuRh2Si2 by the Bridgman method and studied their electronic properties measuring the electrical resistivity under pressure. EuRh2Si2 indicates a first-order valence transition in the pressure range from 1 to 2 GPa, distinguished by a sharp transition and a prominent hysteresis in the temperature dependence of the electrical resistivity. A critical end point in the valence transition is estimated as PCEP ≃ 2.05 GPa and TCEP ≃ 170 K. In the pressure range from 2 to 3 GPa, the electrical resistivity is found to exhibit a characteristic behavior for a moderately heavy-fermion compound such as EuIr2Si2. At pressures higher than 3 GPa, the resistivity reveals a normal metallic behavior in a nearly trivalent electronic state. This is the first report on the pressure evolution of the electronic states from the antiferromagnetically ordered state to the moderate heavy-fermion state and nearly trivalent state, via the first-order valence transition.

ジャーナルjournal of the physical society of japan
出版ステータス出版済み - 6月 15 2016

!!!All Science Journal Classification (ASJC) codes

  • 物理学および天文学(全般)


「Pressure-induced valence transition and characteristic electronic states in EuRh2Si2」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。