Preparation of enantioenriched helical- and axial-chiral molecules by dynamic asymmetric induction

Yuuya Kawasaki; Ryota Kamikubo; Yuta Kumegawa; Kouhei Ogawa; Takeru Kashiwagi; Yusuke Ano; Kazunobu Igawa; Katsuhiko Tomooka

doi:10.1039/d1cc05881a

Preparation of enantioenriched helical- and axial-chiral molecules by dynamic asymmetric induction

Yuuya Kawasaki, Ryota Kamikubo, Yuta Kumegawa, Kouhei Ogawa, Takeru Kashiwagi, Yusuke Ano, Kazunobu Igawa, Katsuhiko Tomooka

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

2 被引用数 (Scopus)

抄録

Dynamic asymmetric induction (DYASIN) of racemic dynamic chiral heterohelicenes afforded their highly enantioenriched forms (up to 96% ep) in quantitative yields. These heterohelicenes were readily converted into semi-static axial-chiral 1,1′-binaphthyl derivatives in a stereospecific manner.

本文言語	英語
ページ（範囲）	1605-1608
ページ数	4
ジャーナル	Chemical Communications
巻	58
号	10
DOI	https://doi.org/10.1039/d1cc05881a
出版ステータス	出版済み - 2月 4 2022

!!!All Science Journal Classification (ASJC) codes

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学一般
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/d1cc05881a

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abstract = "Dynamic asymmetric induction (DYASIN) of racemic dynamic chiral heterohelicenes afforded their highly enantioenriched forms (up to 96% ep) in quantitative yields. These heterohelicenes were readily converted into semi-static axial-chiral 1,1′-binaphthyl derivatives in a stereospecific manner.",

author = "Yuuya Kawasaki and Ryota Kamikubo and Yuta Kumegawa and Kouhei Ogawa and Takeru Kashiwagi and Yusuke Ano and Kazunobu Igawa and Katsuhiko Tomooka",

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T1 - Preparation of enantioenriched helical- and axial-chiral molecules by dynamic asymmetric induction

AU - Kawasaki, Yuuya

AU - Kamikubo, Ryota

AU - Kumegawa, Yuta

AU - Ogawa, Kouhei

AU - Kashiwagi, Takeru

AU - Ano, Yusuke

AU - Igawa, Kazunobu

AU - Tomooka, Katsuhiko

PY - 2022/2/4

Y1 - 2022/2/4

N2 - Dynamic asymmetric induction (DYASIN) of racemic dynamic chiral heterohelicenes afforded their highly enantioenriched forms (up to 96% ep) in quantitative yields. These heterohelicenes were readily converted into semi-static axial-chiral 1,1′-binaphthyl derivatives in a stereospecific manner.

AB - Dynamic asymmetric induction (DYASIN) of racemic dynamic chiral heterohelicenes afforded their highly enantioenriched forms (up to 96% ep) in quantitative yields. These heterohelicenes were readily converted into semi-static axial-chiral 1,1′-binaphthyl derivatives in a stereospecific manner.

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JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Preparation of enantioenriched helical- and axial-chiral molecules by dynamic asymmetric induction

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!!!All Science Journal Classification (ASJC) codes

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