Precursor-film-driven ultra-early depinning of the three-phase contact line

Hypothesis: Despite its importance in colloid and interface science, contact line pinning remains poorly understood, especially in the presence of a precursor film. We hypothesized that this is due to a lack of an experimental method capable of directly observing their physics at the nanoscale. Methods: Using coherence scanning interferometry, we visualized the three-dimensional behavior of contact lines with a precursor film near a nanogroove structure composed of flat terrace surfaces and steps with an inclination angle of 30° while achieving nanoscale vertical resolution. Findings: We found that even when the contact line is pinned at the edge of the step, the precursor film is not and advances beyond the edge. Furthermore, we discovered that the precursor film has two distinct effects on contact line motion. Specifically, the precursor film facilitates depinning when the contact line descends the step — a contact angle change was 0.9°, only 3.0% of the value predicted by a classical theory of contact angle at a solid edge. This ultra-early depinning is attributed to the formation of a new liquid film past the edge, driven by the progression of the precursor film that overcomes the pinning effect. In contrast, when the contact line ascends the step, the precursor film acts as a resistance to movement due to steric interaction.