Oxophilicity as a Descriptor for NO Cleavage Efficiency over Group IX Metal Clusters

Masato Yamaguchi, Yufei Zhang, Satoshi Kudoh, Kohei Koyama, Olga V. Lushchikova, Joost M. Bakker, Fumitaka Mafuné, Fumitaka Mafuné

研究成果: ジャーナルへの寄稿学術誌査読

20 被引用数 (Scopus)

抄録

Iridium and rhodium are group IX elements that can both catalytically reduce NO. To understand the difference in their reactivity toward NO, the adsorption forms of NO onto clusters of Ir and Rh are compared using vibrational spectra, recorded via infrared multiple-photon dissociation spectroscopy. The spectra give evidence for the existence of at least two specific adsorption forms. The main Ir6+NO isomer is one in which NO is dissociated, whereas one other is a local minimum structure in the reaction pathway leading to dissociative adsorption. In contrast to adsorption onto Rh6+, where less than 10% of the isomeric population was found in the global minimum associated with dissociative adsorption, a substantial fraction (about 50%) of NO dissociates on Ir6+. This higher efficiency is attributed to a considerably reduced activation barrier for dissociation on Ir6+. The key chemical property identified for dissociation efficiency is the cluster's affinity to atomic oxygen.

本文言語英語
ページ(範囲)4408-4412
ページ数5
ジャーナルJournal of Physical Chemistry Letters
11
11
DOI
出版ステータス出版済み - 6月 4 2020
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 材料科学一般
  • 物理化学および理論化学

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