TY - JOUR
T1 - One-electron oxidized copper(II) salophen complexes
T2 - Phenoxyl versus diiminobenzene radical species
AU - Kochem, Amélie
AU - Jarjayes, Olivier
AU - Baptiste, Benoit
AU - Philouze, Christian
AU - Vezin, Hervé
AU - Tsukidate, Kazuaki
AU - Tani, Fumito
AU - Orio, Maylis
AU - Shimazaki, Yuichi
AU - Thomas, Fabrice
N1 - Copyright:
Copyright 2012 Elsevier B.V., All rights reserved.
PY - 2012/1/23
Y1 - 2012/1/23
N2 - Where is the radical The π-system of the diiminobenzene bridge adds a putative oxidation site to prophenoxyl copper(II) salophen complexes. It is shown that the bridge is effectively redox active and that the radical site (phenoxyl vs. diiminobenzene bridge) in the above cations is tuned by selective methoxy substitution (see figure).
AB - Where is the radical The π-system of the diiminobenzene bridge adds a putative oxidation site to prophenoxyl copper(II) salophen complexes. It is shown that the bridge is effectively redox active and that the radical site (phenoxyl vs. diiminobenzene bridge) in the above cations is tuned by selective methoxy substitution (see figure).
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U2 - 10.1002/chem.201102882
DO - 10.1002/chem.201102882
M3 - Article
C2 - 22213540
AN - SCOPUS:84855959070
SN - 0947-6539
VL - 18
SP - 1068
EP - 1072
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 4
ER -