TY - JOUR
T1 - Nitrogen-Bridged Metallodiazaporphyrin Dimers
T2 - Synergistic Effects of Nitrogen Bridges and meso-Nitrogen Atoms on Structure and Properties
AU - Kawamata, Masahiro
AU - Sugai, Takuma
AU - Minoura, Mao
AU - Maruyama, Yasuhisa
AU - Furukawa, Ko
AU - Holstrom, Cole
AU - Nemykin, Victor N.
AU - Nakano, Haruyuki
AU - Matano, Yoshihiro
N1 - Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2017/4/4
Y1 - 2017/4/4
N2 - NH-bridged and pyrazine-fused metallodiazaporphyrin dimers have been prepared from nickel(II) and copper(II) complexes of 3-amino-5,15-diazaporphyrin by Pd-catalyzed C−N cross-coupling and oxidative dimerization reactions, respectively. The synergistic effects of the nitrogen bridges and meso-nitrogen atoms play major roles in enhancing the light-harvesting properties and delocalization of an electron spin over the entire π-skeletons of the metallodiazaporphyrin dimers.
AB - NH-bridged and pyrazine-fused metallodiazaporphyrin dimers have been prepared from nickel(II) and copper(II) complexes of 3-amino-5,15-diazaporphyrin by Pd-catalyzed C−N cross-coupling and oxidative dimerization reactions, respectively. The synergistic effects of the nitrogen bridges and meso-nitrogen atoms play major roles in enhancing the light-harvesting properties and delocalization of an electron spin over the entire π-skeletons of the metallodiazaporphyrin dimers.
UR - http://www.scopus.com/inward/record.url?scp=85014400940&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85014400940&partnerID=8YFLogxK
U2 - 10.1002/asia.201700204
DO - 10.1002/asia.201700204
M3 - Article
C2 - 28181737
AN - SCOPUS:85014400940
SN - 1861-4728
VL - 12
SP - 816
EP - 821
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
IS - 7
ER -