Monophosphaporphyrins: Oxidative π-extension at the peripherally fused carbocycle of the phosphaporphyrin ring

Yoshihiro Matano; Makoto Nakashima; Takashi Nakabuchi; Hiroshi Imahori; Shinya Fujishige; Haruyuki Nakano

doi:10.1021/ol7029118

Monophosphaporphyrins: Oxidative π-extension at the peripherally fused carbocycle of the phosphaporphyrin ring

Yoshihiro Matano, Makoto Nakashima, Takashi Nakabuchi, Hiroshi Imahori, Shinya Fujishige, Haruyuki Nakano

複合領域化学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

44 被引用数 (Scopus)

抄録

The 18π-σ^3- and 22π-σ⁴- phosphaporphyrins were successfully prepared by an acid-promoted condensation between a phosphatripyrrane and a 2,5-bis[hydroxy(phenyl)methyl]pyrrole, and their structures, aromaticity, and optical and electrochemical properties were disclosed. Notably, a σ⁴-phosphaporphyrinogen and the 18π-σ³-phosphaporphyrin undergo oxidative π-extension at the peripherally fused carbocycle to afford the 22π-σ⁴- phosphaporphyrin.

本文言語	英語
ページ（範囲）	553-556
ページ数	4
ジャーナル	Organic letters
巻	10
号	4
DOI	https://doi.org/10.1021/ol7029118
出版ステータス	出版済み - 2月 21 2008

!!!All Science Journal Classification (ASJC) codes

生化学
物理化学および理論化学
有機化学

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10.1021/ol7029118

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title = "Monophosphaporphyrins: Oxidative π-extension at the peripherally fused carbocycle of the phosphaporphyrin ring",

abstract = "The 18π-σ3- and 22π-σ4- phosphaporphyrins were successfully prepared by an acid-promoted condensation between a phosphatripyrrane and a 2,5-bis[hydroxy(phenyl)methyl]pyrrole, and their structures, aromaticity, and optical and electrochemical properties were disclosed. Notably, a σ4-phosphaporphyrinogen and the 18π-σ3-phosphaporphyrin undergo oxidative π-extension at the peripherally fused carbocycle to afford the 22π-σ4- phosphaporphyrin.",

author = "Yoshihiro Matano and Makoto Nakashima and Takashi Nakabuchi and Hiroshi Imahori and Shinya Fujishige and Haruyuki Nakano",

year = "2008",

month = feb,

day = "21",

doi = "10.1021/ol7029118",

language = "English",

volume = "10",

pages = "553--556",

journal = "Organic letters",

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TY - JOUR

T1 - Monophosphaporphyrins

T2 - Oxidative π-extension at the peripherally fused carbocycle of the phosphaporphyrin ring

AU - Matano, Yoshihiro

AU - Nakashima, Makoto

AU - Nakabuchi, Takashi

AU - Imahori, Hiroshi

AU - Fujishige, Shinya

AU - Nakano, Haruyuki

PY - 2008/2/21

Y1 - 2008/2/21

N2 - The 18π-σ3- and 22π-σ4- phosphaporphyrins were successfully prepared by an acid-promoted condensation between a phosphatripyrrane and a 2,5-bis[hydroxy(phenyl)methyl]pyrrole, and their structures, aromaticity, and optical and electrochemical properties were disclosed. Notably, a σ4-phosphaporphyrinogen and the 18π-σ3-phosphaporphyrin undergo oxidative π-extension at the peripherally fused carbocycle to afford the 22π-σ4- phosphaporphyrin.

AB - The 18π-σ3- and 22π-σ4- phosphaporphyrins were successfully prepared by an acid-promoted condensation between a phosphatripyrrane and a 2,5-bis[hydroxy(phenyl)methyl]pyrrole, and their structures, aromaticity, and optical and electrochemical properties were disclosed. Notably, a σ4-phosphaporphyrinogen and the 18π-σ3-phosphaporphyrin undergo oxidative π-extension at the peripherally fused carbocycle to afford the 22π-σ4- phosphaporphyrin.

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U2 - 10.1021/ol7029118

DO - 10.1021/ol7029118

M3 - Article

C2 - 18189409

AN - SCOPUS:39749156934

SN - 1523-7060

VL - 10

SP - 553

EP - 556

JO - Organic letters

JF - Organic letters

IS - 4

ER -

Monophosphaporphyrins: Oxidative π-extension at the peripherally fused carbocycle of the phosphaporphyrin ring

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!!!All Science Journal Classification (ASJC) codes

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