Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids

Samir Manna; Shunta Kakumachi; Kanak Kanti Das; Youichi Tsuchiya; Chihaya Adachi; Santanu Panda

doi:10.1039/d2sc02090d

Mechanistic dichotomy in the solvent dependent access to E vs. Z-allylic amines via decarboxylative vinylation of amino acids

Samir Manna, Shunta Kakumachi, Kanak Kanti Das, Youichi Tsuchiya, Chihaya Adachi, Santanu Panda

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

21 被引用数 (Scopus)

抄録

The solvent plays an important role in the photophysical properties of donor-acceptor based photocatalysts. The solvent-dependent access to E vs. Z-allylic amines was achieved via decarboxylative vinylation of amino acids with vinyl sulfones. Detailed experimental studies have been conducted to understand the role of the solvent in the reactivity and stereoselectivity of the vinylation reactions.

本文言語	英語
ページ（範囲）	9678-9684
ページ数	7
ジャーナル	Chemical Science
巻	13
号	33
DOI	https://doi.org/10.1039/d2sc02090d
出版ステータス	出版済み - 7月 21 2022

!!!All Science Journal Classification (ASJC) codes

化学一般

文献へのアクセス

10.1039/d2sc02090d

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引用スタイル

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AU - Adachi, Chihaya

AU - Panda, Santanu

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