TY - JOUR
T1 - Linear, redox-active Pt6 and Pt2Pd2Pt 2 clusters
AU - Goto, Eri
AU - Begum, Rowshan A.
AU - Zhan, Shuzhong
AU - Tanase, Tomoaki
AU - Tanigaki, Katsumi
AU - Sakai, Ken
PY - 2004/9/27
Y1 - 2004/9/27
N2 - A piece of jewelry is the complex [Pt4M2(μ-H) (μ-dpmp)4(XylNC)2](PF6)3 (M = Pt, see structure), which contains the longest platinum chain characterized so far. This complex and the related compound with M = Pd are redox-active and can be readily oxidized to the electron-deficient clusters [Pt4M 2(μ-dpmp)4(XylNC)2](PF6) 4 (M = Pt, Pd) with dynamic structural changes in the metal strings. Xyl = 2,6-dimethylphenyl, dpmp = bis(diphenylphosphanylmethyl)phenylphosphane.
AB - A piece of jewelry is the complex [Pt4M2(μ-H) (μ-dpmp)4(XylNC)2](PF6)3 (M = Pt, see structure), which contains the longest platinum chain characterized so far. This complex and the related compound with M = Pd are redox-active and can be readily oxidized to the electron-deficient clusters [Pt4M 2(μ-dpmp)4(XylNC)2](PF6) 4 (M = Pt, Pd) with dynamic structural changes in the metal strings. Xyl = 2,6-dimethylphenyl, dpmp = bis(diphenylphosphanylmethyl)phenylphosphane.
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U2 - 10.1002/anie.200460707
DO - 10.1002/anie.200460707
M3 - Article
C2 - 15384115
AN - SCOPUS:4944236548
SN - 1433-7851
VL - 43
SP - 5029
EP - 5032
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 38
ER -