Insights into the Dielectric-Heating-Enhanced Regeneration of CO2-Rich Aqueous Amine Solutions

Shuntaro Tsubaki, Kosuke Furusawa, Hidetaka Yamada, Tsuguhiro Kato, Takayuki Higashii, Satoshi Fujii, Yuji Wada

研究成果: ジャーナルへの寄稿学術誌査読

12 被引用数 (Scopus)

抄録

Microwaves (MW) and radio frequency (RF) dielectric heating were used to facilitate the regeneration of CO2-rich amine solutions, and the mechanism of the rate enhancement by dielectric heating was discussed. Dielectric measurements of aqueous solutions of monoethanolamine (primary amine), 2-(ethylamino)ethanol (secondary amine), and N-methyl diethanolamine (tertiary amine) revealed that the formation of carbamate and bicarbonate ions by CO2 absorption improves the dielectric loss tangent. Dielectric heating by MWs (2.45 GHz, 915 MHz) and RF (200 MHz) was compared to facilitate regeneration of the CO2-rich amine solution at a constant power of 40 W. The CO2 release rate was the highest at 2.45 GHz in all aqueous amine solutions, which was 1.47 to 1.74 times that of conventional heating by an oil bath operated at 120 °C. However, the CO2 release rate decreased as the frequency decreased to 915 and 200 MHz. Electromagnetic field simulation suggested that CO2 release was enhanced owing to the generation of a more intense electric field at 2.45 GHz than at lower frequencies.

本文言語英語
ページ(範囲)13593-13599
ページ数7
ジャーナルACS Sustainable Chemistry and Engineering
8
36
DOI
出版ステータス出版済み - 9月 14 2020
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 化学一般
  • 環境化学
  • 化学工学一般
  • 再生可能エネルギー、持続可能性、環境

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