Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

Hironori Nakajima; Toshiyuki Nohira; Yasuhiko Ito

doi:10.1021/jp049490y

Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

Hironori Nakajima
, Toshiyuki Nohira
, Yasuhiko Ito

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

1 被引用数 (Scopus)

抄録

Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm^-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li⁺ ions in the melt.

本文言語	英語
ページ（範囲）	4567-4569
ページ数	3
ジャーナル	Journal of Physical Chemistry A
巻	108
号	21
DOI	https://doi.org/10.1021/jp049490y
出版ステータス	出版済み - 5月 27 2004
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

物理化学および理論化学

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10.1021/jp049490y

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引用スタイル

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title = "Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere",

abstract = "Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.",

author = "Hironori Nakajima and Toshiyuki Nohira and Yasuhiko Ito",

year = "2004",

month = may,

day = "27",

doi = "10.1021/jp049490y",

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pages = "4567--4569",

journal = "Journal of Physical Chemistry A",

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TY - JOUR

T1 - Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

AU - Nakajima, Hironori

AU - Nohira, Toshiyuki

AU - Ito, Yasuhiko

PY - 2004/5/27

Y1 - 2004/5/27

N2 - Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.

AB - Infrared spectroscopy of molten LiCl-KCl eutectic melt under several hydrogen pressures at 673 K provided an absorption band in the wavenumber region of 1300-1600 cm-1. This absorption band is ascribed to the vibration of a Li-H interaction in the melt. On the other hand, the absorption bands ascribed to a K-H interaction and H-Cl interaction were not observed. The existence of the Li-H interaction shows a strong attractive force between dissolved hydrogen atoms and Li+ ions in the melt.

UR - https://www.scopus.com/pages/publications/2942625795

UR - https://www.scopus.com/pages/publications/2942625795#tab=citedBy

U2 - 10.1021/jp049490y

DO - 10.1021/jp049490y

M3 - Article

AN - SCOPUS:2942625795

SN - 1089-5639

VL - 108

SP - 4567

EP - 4569

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 21

ER -

Infrared spectroscopy of molten LiCl-KCl under hydrogen gas atmosphere

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!!!All Science Journal Classification (ASJC) codes

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