Influence of aluminate and silicate on selenate immobilization using alkaline-earth metal oxides and ferrous salt

Quanzhi Tian, Yingchu Bai, Yinhai Pan, Shuo Yao, Changshuai Chen, Haijun Zhang, Keiko Sasaki

研究成果: ジャーナルへの寄稿学術誌査読

1 被引用数 (Scopus)


Effects of aluminate and silicate species on the SeO42− immobilization using alkali-earth metal oxides and ferrous species have not been clearly elucidated. In the present study, Al and Si species were separately added into MgO/Fe(II) and CaO/Fe(II) reactions containing SeO42−, studied by toxicity characteristic leaching procedure (TCLP), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray absorption fine structure (XAFS), and PHREEQC simulation. Approximately 42 % of SeO42− was reduced to SeO32− for MgO/Fe(II) reaction in the presence of Al species, being consistent with the case without Al species. The Al species only showed slight inhibition of Se leaching for the MgO/Fe(II) reaction. Most of Se oxyanions were adsorbed onto Mg(OH)2 through outer-sphere complexation. For CaO/Fe(II) reaction, all of SeO42− was reduced to SeO32− with or without Al species. However, the Se leaching amount (3 %) of sample added with Al species (CE3) is much lower than that (12 %) of sample without Al species (CE2). This is mainly because SeO32− can be sorbed onto the iron-based minerals through binuclear bidentate corner-sharing (2C) complexation instead of monodentate mononuclear corner-sharing (1V) complexation of the case without Al species. On the other hand, SeO42− was not reduced to SeO32− in the presence of silicate, and almost all of Se was leached out for silicate-contained samples except CaO/Fe(II) reaction with the addition of Al species. This is due to the polymerization of Al and Si species under a high-alkalinity environment, thereby stabilizing SeO42− in the amorphous silicon-aluminum structure and contributing to the decrease of Se leaching.

ジャーナルScience of the Total Environment
出版ステータス出版済み - 12月 10 2022

!!!All Science Journal Classification (ASJC) codes

  • 環境工学
  • 環境化学
  • 廃棄物管理と処理
  • 汚染


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