Independent control of phases and defects in TiO2thin films for functional transistor channels

Takeaki Yajima, Go Oike, Tomonori Nishimura, Akira Toriumi

研究成果: ジャーナルへの寄稿学術誌査読

14 被引用数 (Scopus)

抄録

TiO2has various inherent advantages in practical devices: chemical stability, non-toxicity, and abundance on earth, as highlighted in a range of applications of TiO2surfaces in photocatalysis/optoelectronics. However, the application of TiO2to three-terminal devices has been limited; for example, TiO2-channel transistors, which may potentially modulate the TiO2surface properties by electrostatic back gating, has suffered from low field-effect mobility (μFE< 1 cm2V−1s−1) irrespective of fabrication methods. The major challenge is to control phases (rutile/anatase) and defects (oxygen vacancy) simultaneously in TiO2thin films. Here, we achieved μFE∼ 10 cm2V−1s−1in TiO2-channel transistors, one order higher than before and even comparable to InGaZnO channels. The major improvement is the independent control of phases and defects in TiO2thin films; we formed short-range order of anatase phase in the amorphous deposition, and minimized the number of defects in the subsequent thermal treatment. Besides, we showed this independent control of phases and defects are underpinned by excellent thermal stability of TiO2/SiO2interfaces. These results demonstrate TiO2can be a transistor channel with a reasonable μFEand ON/OFF ratio (>6 orders), not only changing the conventional image of this material, but also promising new functionalities based on unique properties of TiO2.

本文言語英語
ページ(範囲)2196-2202
ページ数7
ジャーナルPhysica Status Solidi (A) Applications and Materials Science
213
8
DOI
出版ステータス出版済み - 8月 1 2016
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 表面および界面
  • 表面、皮膜および薄膜
  • 電子工学および電気工学
  • 材料化学

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