Highly symmetric 3D ferrimagnets, [Mn(dien)]3[M(CN) 6]2·2H2O (M = Cr, Mn; Dien = diethylenetriamine): Synthesis, structures and magnetic properties

Wakako Kaneko; Akio Mishima; Hisayoshi Ohba; Susumu Kitagawa; Masaaki Ohba

doi:10.1016/j.poly.2013.03.006

Highly symmetric 3D ferrimagnets, [Mn(dien)]₃[M(CN) ₆]₂·2H₂O (M = Cr, Mn; Dien = diethylenetriamine): Synthesis, structures and magnetic properties

Wakako Kaneko, Akio Mishima, Hisayoshi Ohba, Susumu Kitagawa, Masaaki Ohba

無機・分析化学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

4 被引用数 (Scopus)

抄録

Cyanide-bridged Mn^IIM^III coordination polymers, [Mn(dien)]₃[M(CN)₆]₂·2H₂O (M = Cr (1), Mn (2); dien = diethylenetriamine), have been prepared by using [M(CN)₆]^3- building units and a tridentate dien as a coligand. Single crystal and powder X-ray diffraction results of 1 and 2 proposed that the compounds are isomorphous and form a highly symmetric 3D network based on M₈Mn₁₂ cubes consist of [Mn(dien)] ²⁺ cations and μ₆-, μ₄-, and unbridged [M(CN)₆]^3- anions. Both compounds exhibited a ferrimagnetic ordering at 63.4 K (1) and 24.8 K (2) with coercive field of ∼0 G (1) and 1 kG (2). Their magnetic properties were compared with other cyanide-bridged Mn^IIM^III ferrimagnets and the differences were discussed based on the structure and the electric configuration.

本文言語	英語
ページ（範囲）	122-127
ページ数	6
ジャーナル	Polyhedron
巻	64
DOI	https://doi.org/10.1016/j.poly.2013.03.006
出版ステータス	出版済み - 2013

!!!All Science Journal Classification (ASJC) codes

物理化学および理論化学
無機化学
材料化学

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10.1016/j.poly.2013.03.006

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「Highly symmetric 3D ferrimagnets, [Mn(dien)]₃[M(CN) ₆]₂·2H₂O (M = Cr, Mn; Dien = diethylenetriamine): Synthesis, structures and magnetic properties」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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title = "Highly symmetric 3D ferrimagnets, [Mn(dien)]3[M(CN) 6]2·2H2O (M = Cr, Mn; Dien = diethylenetriamine): Synthesis, structures and magnetic properties",

abstract = "Cyanide-bridged MnIIMIII coordination polymers, [Mn(dien)]3[M(CN)6]2·2H2O (M = Cr (1), Mn (2); dien = diethylenetriamine), have been prepared by using [M(CN)6]3- building units and a tridentate dien as a coligand. Single crystal and powder X-ray diffraction results of 1 and 2 proposed that the compounds are isomorphous and form a highly symmetric 3D network based on M8Mn12 cubes consist of [Mn(dien)] 2+ cations and μ6-, μ4-, and unbridged [M(CN)6]3- anions. Both compounds exhibited a ferrimagnetic ordering at 63.4 K (1) and 24.8 K (2) with coercive field of ∼0 G (1) and 1 kG (2). Their magnetic properties were compared with other cyanide-bridged MnIIMIII ferrimagnets and the differences were discussed based on the structure and the electric configuration.",

author = "Wakako Kaneko and Akio Mishima and Hisayoshi Ohba and Susumu Kitagawa and Masaaki Ohba",

note = "Funding Information: This work was supported by a Grant-In-Aid for Science Research in a Priority Area {\textquoteleft}Coordination Programming (No. 24108102 ){\textquoteright} and a Grant-In-Aid for Scientific Research Program (No. 23245014 ) from the Ministry of Education, Culture, Sports, Science and Technology of Japan . ",

year = "2013",

doi = "10.1016/j.poly.2013.03.006",

language = "English",

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T2 - Synthesis, structures and magnetic properties

AU - Kaneko, Wakako

AU - Mishima, Akio

AU - Ohba, Hisayoshi

AU - Kitagawa, Susumu

AU - Ohba, Masaaki

N1 - Funding Information: This work was supported by a Grant-In-Aid for Science Research in a Priority Area ‘Coordination Programming (No. 24108102 )’ and a Grant-In-Aid for Scientific Research Program (No. 23245014 ) from the Ministry of Education, Culture, Sports, Science and Technology of Japan .

PY - 2013

Y1 - 2013

N2 - Cyanide-bridged MnIIMIII coordination polymers, [Mn(dien)]3[M(CN)6]2·2H2O (M = Cr (1), Mn (2); dien = diethylenetriamine), have been prepared by using [M(CN)6]3- building units and a tridentate dien as a coligand. Single crystal and powder X-ray diffraction results of 1 and 2 proposed that the compounds are isomorphous and form a highly symmetric 3D network based on M8Mn12 cubes consist of [Mn(dien)] 2+ cations and μ6-, μ4-, and unbridged [M(CN)6]3- anions. Both compounds exhibited a ferrimagnetic ordering at 63.4 K (1) and 24.8 K (2) with coercive field of ∼0 G (1) and 1 kG (2). Their magnetic properties were compared with other cyanide-bridged MnIIMIII ferrimagnets and the differences were discussed based on the structure and the electric configuration.

AB - Cyanide-bridged MnIIMIII coordination polymers, [Mn(dien)]3[M(CN)6]2·2H2O (M = Cr (1), Mn (2); dien = diethylenetriamine), have been prepared by using [M(CN)6]3- building units and a tridentate dien as a coligand. Single crystal and powder X-ray diffraction results of 1 and 2 proposed that the compounds are isomorphous and form a highly symmetric 3D network based on M8Mn12 cubes consist of [Mn(dien)] 2+ cations and μ6-, μ4-, and unbridged [M(CN)6]3- anions. Both compounds exhibited a ferrimagnetic ordering at 63.4 K (1) and 24.8 K (2) with coercive field of ∼0 G (1) and 1 kG (2). Their magnetic properties were compared with other cyanide-bridged MnIIMIII ferrimagnets and the differences were discussed based on the structure and the electric configuration.

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