High pressure effect on optical properties of cerium ion in fluoroaluminate glass

N. Kitamura, K. Fukumi, J. Nishii, M. Makihara, T. Sasaki, N. Ohno

研究成果: ジャーナルへの寄稿会議記事査読

7 被引用数 (Scopus)


High pressure effects on optical properties of Ce3+ doped ternary fluoroaluminate (18BaF2·37CaF2·45AlF3) glass have been investigated in terms of ligand field around cerium ion. Five bands due to the 4f-5d transitions were observed in ultraviolet absorption spectra for the glass. A photoluminescence band was observed at around 300 nm under excitation at each band. The photoluminescence band shifted toward smaller energies by densifying the glass using high pressures and temperatures. An energy shift of the band was also found in in situ photoluminescence measurement under high pressure using a sapphire anvil cell. However, the shift observed under high pressure was large compared with that of the densified glass. We deduced that the large peak shift under high pressure is mainly due to a local elastic contraction around cerium ion.

ジャーナルJournal of Non-Crystalline Solids
出版ステータス出版済み - 11月 2 1999
イベントProceedings of the 1998 Symposium on Advances in Photonic Glasses - Kyongju, Korea
継続期間: 9月 20 19989月 23 1998

!!!All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • セラミックおよび複合材料
  • 凝縮系物理学
  • 材料化学


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