(Hexafluoroacetylacetonato)copper(i)-cycloalkyne complexes as protected cycloalkynes

Naoaki Makio; Yuki Sakata; Tomoko Kuribara; Keisuke Adachi; Yasutomo Hatakeyama; Tomohiro Meguro; Kazunobu Igawa; Katsuhiko Tomooka; Takamitsu Hosoya; Suguru Yoshida

doi:10.1039/d0cc05182a

(Hexafluoroacetylacetonato)copper(i)-cycloalkyne complexes as protected cycloalkynes

Naoaki Makio, Yuki Sakata, Tomoko Kuribara, Keisuke Adachi, Yasutomo Hatakeyama, Tomohiro Meguro, Kazunobu Igawa, Katsuhiko Tomooka, Takamitsu Hosoya, Suguru Yoshida

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

7 被引用数 (Scopus)

抄録

A protection method for cycloalkynes by the formation of (hexafluoroacetylacetonato)copper(i)-cycloalkyne complexes is disclosed. Various complexes having functional groups were efficiently prepared, which are easily purified by silica-gel column chromatography. Selective click reactions were realized through the complexation of cycloalkynes with copper.

本文言語	英語
ページ（範囲）	11449-11452
ページ数	4
ジャーナル	Chemical Communications
巻	56
号	77
DOI	https://doi.org/10.1039/d0cc05182a
出版ステータス	出版済み - 10月 4 2020

!!!All Science Journal Classification (ASJC) codes

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学一般
表面、皮膜および薄膜
金属および合金
材料化学

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title = "(Hexafluoroacetylacetonato)copper(i)-cycloalkyne complexes as protected cycloalkynes",

abstract = "A protection method for cycloalkynes by the formation of (hexafluoroacetylacetonato)copper(i)-cycloalkyne complexes is disclosed. Various complexes having functional groups were efficiently prepared, which are easily purified by silica-gel column chromatography. Selective click reactions were realized through the complexation of cycloalkynes with copper.",

author = "Naoaki Makio and Yuki Sakata and Tomoko Kuribara and Keisuke Adachi and Yasutomo Hatakeyama and Tomohiro Meguro and Kazunobu Igawa and Katsuhiko Tomooka and Takamitsu Hosoya and Suguru Yoshida",

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year = "2020",

month = oct,

day = "4",

doi = "10.1039/d0cc05182a",

language = "English",

volume = "56",

pages = "11449--11452",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - (Hexafluoroacetylacetonato)copper(i)-cycloalkyne complexes as protected cycloalkynes

AU - Makio, Naoaki

AU - Sakata, Yuki

AU - Kuribara, Tomoko

AU - Adachi, Keisuke

AU - Hatakeyama, Yasutomo

AU - Meguro, Tomohiro

AU - Igawa, Kazunobu

AU - Tomooka, Katsuhiko

AU - Hosoya, Takamitsu

AU - Yoshida, Suguru

PY - 2020/10/4

Y1 - 2020/10/4

N2 - A protection method for cycloalkynes by the formation of (hexafluoroacetylacetonato)copper(i)-cycloalkyne complexes is disclosed. Various complexes having functional groups were efficiently prepared, which are easily purified by silica-gel column chromatography. Selective click reactions were realized through the complexation of cycloalkynes with copper.

AB - A protection method for cycloalkynes by the formation of (hexafluoroacetylacetonato)copper(i)-cycloalkyne complexes is disclosed. Various complexes having functional groups were efficiently prepared, which are easily purified by silica-gel column chromatography. Selective click reactions were realized through the complexation of cycloalkynes with copper.

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UR - http://www.scopus.com/inward/citedby.url?scp=85091890856&partnerID=8YFLogxK

U2 - 10.1039/d0cc05182a

DO - 10.1039/d0cc05182a

M3 - Article

C2 - 32852507

AN - SCOPUS:85091890856

SN - 1359-7345

VL - 56

SP - 11449

EP - 11452

JO - Chemical Communications

JF - Chemical Communications

IS - 77

ER -

(Hexafluoroacetylacetonato)copper(i)-cycloalkyne complexes as protected cycloalkynes

抄録

!!!All Science Journal Classification (ASJC) codes

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