@article{ac28c52d6cb4492b9e93dc42b3a71f0b,
title = "Hexafluoro complex of rutherfordium in mixed HF/HNO3 solutions",
abstract = "Formation of anionic fluoride-complexes of element 104, rutherfordium, produced in the 248Cm(18O, 5n)261Rf reaction was studied by anion-exchange on an atom-at-a-time scale. It was found that the hexafluoro complex of Rf, [RfF6]2-, was formed in the studied fluoride ion concentrations of 0.0005-0.013 M. Formation of [RfF 6]2- was significantly different from that of the homologues Zr and Hf, [ZrF6]2- and [HfF6] 2-; the evaluated formation constant of [RfF6] 2- is at least one-order of magnitude smaller than those of [ZrF 6]2- and [HfF6]2-.",
keywords = "Anion-exchange chromatography, Atom-at-a-time chemistry, Hafnium (Hf), Hexafluoro complex, Rutherfordium (Rf), Zirconium (Zr)",
author = "A. Toyoshima and H. Haba and K. Tsukada and M. Asai and K. Akiyama and S. Goto and Y. Ishii and I. Nishinaka and Sato, \{T. K.\} and Y. Nagame and W. Sato and Y. Tani and H. Hasegawa and K. Matsuo and D. Saika and Y. Kitamoto and A. Shinohara and M. Ito and J. Saito and H. Kudo and A. Yokoyama and M. Sakama and K. Sueki and Y. Oura and H. Nakahara and M. Sch{\"a}del and W. Br{\"u}chle and Kratz, \{J. V.\}",
note = "Funding Information: Acknowledgment. The authors express their gratitude to the crew of the JAEA tandem accelerator for their invaluable assistance in the course of these experiments. This work was supported in part by the JAEA-University Collaboration Research Project and the Program on the Scientific Cooperation between JAEA and GSI in Research and Development in the Field of Ion Beam Application.",
year = "2008",
doi = "10.1524/ract.2008.1474",
language = "English",
volume = "96",
pages = "125--134",
journal = "Radiochimica Acta",
issn = "0033-8230",
publisher = "Walter de Gruyter GmbH",
number = "3",
}