Fate of Higher-Mass Elements and Surface Functional Groups during the Pyrolysis of Waste Pecan Shell

Keith Jones, Girish Ramakrishnan, Minori Uchimiya, Alexander Orlov, Marco J. Castaldi, Jeffrey Leblanc, Syuntaro Hiradate

研究成果: ジャーナルへの寄稿学術誌査読

19 被引用数 (Scopus)


Thermochemical conversion of agricultural wastes to bioenergy has a potential to play forefront roles within the context of the food, energy, and water nexus. The biochar solid product of pyrolysis is a promising tool to manage food crop production and water resources by means of soil amendment. The goal of this study was to understand the fate of surface functional groups and higher-atomic-mass elements during the pyrolysis of pecan shell, which is known to accumulate calcium oxalate. Pecan shell feedstock and biochars were analyzed ex situ using X-ray computed microtomography and solid-state 13C cross-polarization and magic-angle-spinning NMR spectroscopy; the pyrolysis kinetics was monitored in situ by thermogravimetric analysis-gas chromatography (TGA-GC). The NMR spectra indicated the greatest (i) reduction in O/N alkyl functionality and (ii) increase in the aromatic peak between 300 and 500 °C. Primary physical transformation was observed near 400 °C in the tomography slice images and corresponding attenuation coefficients. Key changes in physical structure (microtomography) as well as chemical constituents (solid-state NMR) of pecan shell at 300-500 °C coincided with the evolution of gaseous products (hydrogen, methane, carbon monoxide, carbon dioxide, ethylene, and ethane, as monitored in situ by TGA-GC) occurring at 200-500 °C. These observations followed the reported (i) formation and removal of carboxyl surface functional groups of biochar and (ii) conversion of calcium oxalate to carbonate, both occurring at the key transition temperature near 400 °C. Combined with the mass balance (99.7%) obtained for gas-, liquid-, and solid-phase products, these findings will facilitate reactor design to optimize syngas and bio-oil yields and manipulate the surface reactivity of biochar soil amendment.

ジャーナルEnergy and Fuels
出版ステータス出版済み - 12月 17 2015

!!!All Science Journal Classification (ASJC) codes

  • 化学工学一般
  • 燃料技術
  • エネルギー工学および電力技術


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