Facile, convenient synthesis of highly pure ω-ferrocenylalkanethiols as probes for self-assembled monolayer (sam) on gold surface

Masato Tazaki; Kenji Okada; Kenshi Yakata; Koji Nakano; Masashi Sakai; Tadashi Yonemitsu

doi:10.1080/10426500008082402

Facile, convenient synthesis of highly pure ω-ferrocenylalkanethiols as probes for self-assembled monolayer (sam) on gold surface

Masato Tazaki
, Kenji Okada
, Kenshi Yakata
, Koji Nakano
, Masashi Sakai
, Tadashi Yonemitsu

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

9 被引用数 (Scopus)

抄録

High purity synthesis of ω-ferrocenylalkanethiols (Fc(CH₂)_n-SH, n=6, 8, 11) was developed for their use in self-assembled monolayers on gold surface. The method employs a separation and purification of isothiuronium salt 6 to improve the purity of final products 7. The use of hazardous mercury in the Clemmensen reduction of acylferrocene 4 to alkylferrocenes 5 is avoided by an alternative LAH/AlCl₃ reduction.

本文言語	英語
ページ（範囲）	239-249
ページ数	11
ジャーナル	Phosphorus, Sulfur and Silicon and Related Elements
巻	167
DOI	https://doi.org/10.1080/10426500008082402
出版ステータス	出版済み - 2000

!!!All Science Journal Classification (ASJC) codes

生化学
有機化学
無機化学

文献へのアクセス

10.1080/10426500008082402

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引用スタイル

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abstract = "High purity synthesis of ω-ferrocenylalkanethiols (Fc(CH2)n-SH, n=6, 8, 11) was developed for their use in self-assembled monolayers on gold surface. The method employs a separation and purification of isothiuronium salt 6 to improve the purity of final products 7. The use of hazardous mercury in the Clemmensen reduction of acylferrocene 4 to alkylferrocenes 5 is avoided by an alternative LAH/AlCl3 reduction.",

author = "Masato Tazaki and Kenji Okada and Kenshi Yakata and Koji Nakano and Masashi Sakai and Tadashi Yonemitsu",

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AU - Nakano, Koji

AU - Sakai, Masashi

AU - Yonemitsu, Tadashi

PY - 2000

Y1 - 2000

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