TY - JOUR
T1 - Energy efficient green synthesized MOF-801 for adsorption cooling applications
AU - Jahan, Israt
AU - Rupam, Tahmid Hasan
AU - Palash, M. L.
AU - Rocky, Kaiser Ahmed
AU - Saha, Bidyut Baran
N1 - Publisher Copyright:
© 2021 Elsevier B.V.
PY - 2022/1/1
Y1 - 2022/1/1
N2 - Utilization of water as a refrigerant in adsorption cooling systems is a challenging task due to the unavailability of suitable adsorbents. Recently, a new class of porous material, metal–organic frameworks (MOFs), is heightening interest as the potential adsorbent for water adsorption due to its crucial S-shaped adsorption isotherm characteristics. Additionally, the high surface area, large pore volume, and higher affinity towards water vapor outshined MOFs over other porous materials to be used as adsorbent in water-based adsorption cooling system (ACS). However, their industrial production could be obstructed due to economic and ecological limitations. Therefore, in this study, an energy-efficient, environment friendly, rapid and ultrasonication assisted room temperature green synthesis procedure for MOF-801 is reported with additional finding of optimum synthesis condition. Several characterization techniques are employed to ensure the structural stability of the synthesized MOFs and their applicability in ACS. The reaction time of the green synthesized MOF-801 was reduced by eight times than the conventional one while ensuring excellent system performance, which makes this process promising for industrial production.
AB - Utilization of water as a refrigerant in adsorption cooling systems is a challenging task due to the unavailability of suitable adsorbents. Recently, a new class of porous material, metal–organic frameworks (MOFs), is heightening interest as the potential adsorbent for water adsorption due to its crucial S-shaped adsorption isotherm characteristics. Additionally, the high surface area, large pore volume, and higher affinity towards water vapor outshined MOFs over other porous materials to be used as adsorbent in water-based adsorption cooling system (ACS). However, their industrial production could be obstructed due to economic and ecological limitations. Therefore, in this study, an energy-efficient, environment friendly, rapid and ultrasonication assisted room temperature green synthesis procedure for MOF-801 is reported with additional finding of optimum synthesis condition. Several characterization techniques are employed to ensure the structural stability of the synthesized MOFs and their applicability in ACS. The reaction time of the green synthesized MOF-801 was reduced by eight times than the conventional one while ensuring excellent system performance, which makes this process promising for industrial production.
UR - http://www.scopus.com/inward/record.url?scp=85117803021&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85117803021&partnerID=8YFLogxK
U2 - 10.1016/j.molliq.2021.117760
DO - 10.1016/j.molliq.2021.117760
M3 - Article
AN - SCOPUS:85117803021
SN - 0167-7322
VL - 345
JO - Journal of Molecular Liquids
JF - Journal of Molecular Liquids
M1 - 117760
ER -