TY - JOUR
T1 - Electronic and vibrational spectra of aniline-benzene hetero-dimer and aniline homo-dimer ions
AU - Ohashi, Kazuhiko
AU - Inokuchi, Yoshiya
AU - Izutsu, Hironobu
AU - Hino, Kazuyuki
AU - Yamamoto, Norifumi
AU - Nishi, Nobuyuki
AU - Sekiya, Hiroshi
N1 - Funding Information:
This work was supported in part by the Joint Studies Program (1999) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (Nos. 09740450 and 11440177) from the Ministry of Education, Science, Sports and Culture of Japan.
PY - 2000/6/9
Y1 - 2000/6/9
N2 - Structures of (aniline-benzene)+ and (aniline)2+ are re-investigated by electronic spectroscopy in the near-infrared region and vibrational spectroscopy in the NH stretching region. The spectra of (aniline-benzene)+ indicate a structure including a hydrogen bond between an NH bond of the ionic aniline and the π-electrons of the neutral benzene. Two isomers are suggested for (aniline)2+ in which an NH bond of the ionic aniline forms different types of hydrogen bond with the neutral aniline: one with the π-electrons of the aromatic ring and the other with the lone pair of the nitrogen atom.
AB - Structures of (aniline-benzene)+ and (aniline)2+ are re-investigated by electronic spectroscopy in the near-infrared region and vibrational spectroscopy in the NH stretching region. The spectra of (aniline-benzene)+ indicate a structure including a hydrogen bond between an NH bond of the ionic aniline and the π-electrons of the neutral benzene. Two isomers are suggested for (aniline)2+ in which an NH bond of the ionic aniline forms different types of hydrogen bond with the neutral aniline: one with the π-electrons of the aromatic ring and the other with the lone pair of the nitrogen atom.
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U2 - 10.1016/S0009-2614(00)00497-8
DO - 10.1016/S0009-2614(00)00497-8
M3 - Article
AN - SCOPUS:0002682971
SN - 0009-2614
VL - 323
SP - 43
EP - 48
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-2
ER -