Efficient Decarbonylation of Furfural to Furan Catalyzed by Zirconia-Supported Palladium Clusters with Low Atomicity

Tamao Ishida, Kurumi Kume, Kota Kinjo, Tetsuo Honma, Kengo Nakada, Hironori Ohashi, Takushi Yokoyama, Akiyuki Hamasaki, Haruno Murayama, Yusuke Izawa, Masaru Utsunomiya, Makoto Tokunaga

研究成果: ジャーナルへの寄稿学術誌査読

49 被引用数 (Scopus)


Decarbonylation of furfural to furan was efficiently catalyzed by ZrO2-supported Pd clusters in the liquid phase under a N2atmosphere without additives. Although Pd/C and Pd/Al2O3have frequently been used for decarbonylation, Pd/ZrO2exhibited superior catalytic performance compared with these conventional catalysts. Transmission electron microscopy and X-ray absorption fine structure measurements revealed that the size of the Pd particles decreased with an increase in the specific surface area of ZrO2. ZrO2with a high surface area immobilized Pd as clusters consisting of several (three to five) Pd atoms, whereas Pd aggregated to form nanoparticles on other supports such as carbon and Al2O3despite their high surface areas. The catalytic activity of Pd/ZrO2was enhanced with a decrease in particle size, and the smallest Pd/ZrO2was the most active catalyst for decarbonylation. When CeO2was used as the support, a decrease in Pd particle size with an increase in surface area was also observed. Single Pd atoms were deposited on CeO2with a high surface area, with a strong interaction through the formation of a Pd−O−Ce bond, which led to a lower catalytic activity than that of Pd/ZrO2. This result suggests that zero-valent small Pd clusters consisting of more than one Pd atom are the active species for the decarbonylation reaction. Recycling tests proved that Pd/ZrO2maintained its catalytic activity until its sixth use.

出版ステータス出版済み - 12月 20 2016

!!!All Science Journal Classification (ASJC) codes

  • 環境化学
  • 化学工学一般
  • 材料科学一般
  • エネルギー一般


「Efficient Decarbonylation of Furfural to Furan Catalyzed by Zirconia-Supported Palladium Clusters with Low Atomicity」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。