Effect of Catalyst Support in B12Based Heterogeneous Catalysts for Catalytic Alkane Oxidations

Jiamin Cheng, Hikaru Matsumoto, Keita Shichijo, Yoshiko Miura, Hisashi Shimakoshi

研究成果: ジャーナルへの寄稿学術誌査読

抄録

Heterogeneous catalysts composed of a vitamin B12 derivative with a polymer or mesoporous silica were synthesized and characterized. These two types of catalysts were used in alkane oxidation reactions with mCPBA oxidant, and improved catalytic efficiency was obtained using the polymer supported B12 catalyst with a monolith structure compared to that of the monomeric B12 catalyst. The catalytic effects were also evaluated in several alkane substrates and the polymer supported B12 catalyst showed a better performance in all reactions compared to the silica-supported B12 catalyst.

本文言語英語
ページ(範囲)1250-1252
ページ数3
ジャーナルBulletin of the Chemical Society of Japan
95
8
DOI
出版ステータス出版済み - 2022

!!!All Science Journal Classification (ASJC) codes

  • 化学一般

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