Development of a Minimal Photosystem for Hydrogen Production in Inorganic Chemical Cells

Keita Nakanishi, Geoffrey J.T. Cooper, Laurie J. Points, Leanne G. Bloor, Masaaki Ohba, Leroy Cronin

研究成果: ジャーナルへの寄稿学術誌査読

10 被引用数 (Scopus)

抄録

Inorganic chemical cells (iCHELLs) are compartment structures consisting of polyoxometalates (POMs) and cations, offering structured and confined reaction spaces bounded by membranes. We have constructed a system capable of efficient anisotropic and hierarchical photo-induced electron transfer across the iCHELL membrane. Mimicking photosynthesis, our system uses proton gradients between the compartment and the bulk to drive efficient conversion of light into chemical energy, producing hydrogen upon irradiation. This illustrates the power of the iCHELL approach for catalysis, where the structure, compartmentalisation and variation in possible components could be utilised to approach a wide range of reactions.

本文言語英語
ページ(範囲)13066-13070
ページ数5
ジャーナルAngewandte Chemie - International Edition
57
40
DOI
出版ステータス出版済み - 10月 1 2018

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学一般

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