Design and synthesis of enantiomerically pure chiral sandwichlike lamellar structure: New explorations from molecular building blocks to three-dimensional morphology

Zhaomin Hao, Shuyan Song, Shengqun Su, Xuezhi Song, Min Zhu, Shuna Zhao, Xing Meng, Hongjie Zhang

研究成果: ジャーナルへの寄稿学術誌査読

7 被引用数 (Scopus)

抄録

This article reports a pair of novel chiral sandwichlike complexes for the first time. In the two complexes, lanthanide Eu3+ ions and Na+ ions are sandwiched between Schiff base ligands, resulting in a two-dimensional plane. For both of the complexes, the intraplane and interplane interactions are utterly different. The adjacent planes are held together by weak van der Waals forces, while the single plane is formed by covalently bonded intraplane N-Eu-O, O-Eu-O, and O-Na-O atoms. On the basis of this characteristic information derived from their molecular building blocks, we studied three-dimensional morphology which has good agreement with expected lamellar morphology. Furthermore, to examine the chiroptical and stable activities, the CD spectra were investigated in the solution of methanol and five different solid forms.

本文言語英語
ページ(範囲)976-980
ページ数5
ジャーナルCrystal Growth and Design
13
3
DOI
出版ステータス出版済み - 3月 6 2013
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 化学一般
  • 材料科学一般
  • 凝縮系物理学

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