Cycloaddition Initiated by Ynolates: High-Energy Dianion Equivalents as a Molecular Glue

研究成果: ジャーナルへの寄稿学術誌査読

4 被引用数 (Scopus)

抄録

In this paper, ynolate-initiated cycloaddition (annulation) to form a range of carbocycles and heterocycles is described. Ynolates consist of a ketene anion equivalent, which contains both nucleophilic and electrophilic moieties, and a carbodianion equivalent that achieves double addition. Hence, in addition to the usual [n+2] cycloaddition, ynolates can perform formal [n+1]-type annulations. Their high-energy performance has been demonstrated by their triple addition to arynes to generate triptycenes, in which the C?C triple bond of ynolates is cleaved. The synthetic applications of these methods, including natural products synthesis, are also described.

本文言語英語
ページ(範囲)531-545
ページ数15
ジャーナルSynlett
33
6
DOI
出版ステータス出版済み - 4月 1 2022

!!!All Science Journal Classification (ASJC) codes

  • 有機化学

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