Comparison of interdiffusion behavior between linear polystyrenes and cyclic polystyrenes with same molecular weight

Daisuke Kawaguchi; Atsushi Takano; Yushu Matsushita; Naoya Torikai; Keiji Tanaka; Toshihiko Nagamura; Robert Dalgliesh; Sean Langridge

Comparison of interdiffusion behavior between linear polystyrenes and cyclic polystyrenes with same molecular weight

Daisuke Kawaguchi, Atsushi Takano, Yushu Matsushita, Naoya Torikai, Keiji Tanaka, Toshihiko Nagamura, Robert Dalgliesh, Sean Langridge

研究成果: 会議への寄与タイプ › 学会誌 › 査読

抄録

Time evolution of interfacial thicknesses between a cyclic polystyrene (c-hPS) / its deuterated counterpart (c-dPS) and a linear polystyrene (1-hPS) / its deuterated counterpart (1-dPS) bilayer films was investigated by dynamic secondary ion mass spectrometry (DSIMS) and neutron reflectivity (NR). The interfacial thickness of (c-hPS/c-dPS) film was significantly larger than that of (1-hPS/1-dPS) film at any given annealing time, indicating that the diffusion constant of c-PS is constantly larger than that of 1-PS. It might be explained that weaker topological constraint comes from the entanglement for the c-PS than for the 1-PS.

本文言語	英語
ページ	2843
ページ数	1
出版ステータス	出版済み - 2005
イベント	54th SPSJ Symposium on Macromolecules - Yamagata, 日本継続期間: 9月 20 2005 → 9月 22 2005

その他

その他	54th SPSJ Symposium on Macromolecules
国/地域	日本
City	Yamagata
Period	9/20/05 → 9/22/05

!!!All Science Journal Classification (ASJC) codes

工学（全般）

他のファイルとリンク

引用スタイル

@conference{a22da8ac0d944d5d86a789ff4e08c4af,

title = "Comparison of interdiffusion behavior between linear polystyrenes and cyclic polystyrenes with same molecular weight",

abstract = "Time evolution of interfacial thicknesses between a cyclic polystyrene (c-hPS) / its deuterated counterpart (c-dPS) and a linear polystyrene (1-hPS) / its deuterated counterpart (1-dPS) bilayer films was investigated by dynamic secondary ion mass spectrometry (DSIMS) and neutron reflectivity (NR). The interfacial thickness of (c-hPS/c-dPS) film was significantly larger than that of (1-hPS/1-dPS) film at any given annealing time, indicating that the diffusion constant of c-PS is constantly larger than that of 1-PS. It might be explained that weaker topological constraint comes from the entanglement for the c-PS than for the 1-PS.",

author = "Daisuke Kawaguchi and Atsushi Takano and Yushu Matsushita and Naoya Torikai and Keiji Tanaka and Toshihiko Nagamura and Robert Dalgliesh and Sean Langridge",

year = "2005",

language = "English",

pages = "2843",

note = "54th SPSJ Symposium on Macromolecules ; Conference date: 20-09-2005 Through 22-09-2005",

}

TY - CONF

T1 - Comparison of interdiffusion behavior between linear polystyrenes and cyclic polystyrenes with same molecular weight

AU - Kawaguchi, Daisuke

AU - Takano, Atsushi

AU - Matsushita, Yushu

AU - Torikai, Naoya

AU - Tanaka, Keiji

AU - Nagamura, Toshihiko

AU - Dalgliesh, Robert

AU - Langridge, Sean

PY - 2005

Y1 - 2005

N2 - Time evolution of interfacial thicknesses between a cyclic polystyrene (c-hPS) / its deuterated counterpart (c-dPS) and a linear polystyrene (1-hPS) / its deuterated counterpart (1-dPS) bilayer films was investigated by dynamic secondary ion mass spectrometry (DSIMS) and neutron reflectivity (NR). The interfacial thickness of (c-hPS/c-dPS) film was significantly larger than that of (1-hPS/1-dPS) film at any given annealing time, indicating that the diffusion constant of c-PS is constantly larger than that of 1-PS. It might be explained that weaker topological constraint comes from the entanglement for the c-PS than for the 1-PS.

AB - Time evolution of interfacial thicknesses between a cyclic polystyrene (c-hPS) / its deuterated counterpart (c-dPS) and a linear polystyrene (1-hPS) / its deuterated counterpart (1-dPS) bilayer films was investigated by dynamic secondary ion mass spectrometry (DSIMS) and neutron reflectivity (NR). The interfacial thickness of (c-hPS/c-dPS) film was significantly larger than that of (1-hPS/1-dPS) film at any given annealing time, indicating that the diffusion constant of c-PS is constantly larger than that of 1-PS. It might be explained that weaker topological constraint comes from the entanglement for the c-PS than for the 1-PS.

UR - http://www.scopus.com/inward/record.url?scp=33645650393&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645650393&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33645650393

SP - 2843

T2 - 54th SPSJ Symposium on Macromolecules

Y2 - 20 September 2005 through 22 September 2005

ER -

Comparison of interdiffusion behavior between linear polystyrenes and cyclic polystyrenes with same molecular weight

抄録

その他

!!!All Science Journal Classification (ASJC) codes

他のファイルとリンク

フィンガープリント

引用スタイル